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Positronium lifetimes and gas permeation in Aquivion® for fuel cells

机译:Aquivion®中用于燃料电池的正电子寿命和气体渗透

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摘要

Variations of ortho-positronium (o-Ps) lifetime and gas permeability of the Aquivion® E8705 membrane were studied as functions of temperature under vacuum and relative humidity at room temperature. When the temperature was varied between 0 and 100 ℃ in vacuum, the hole volume of Aquivion® E8705, deduced from o-Ps lifetime, gradually increased. However, when the relative humidity was changed at room temperature, the hole volume was essentially unchanged. Good linear correlations between the logarithm of permeabilities of O_2 and H_2 and reciprocal hole volume at different temperatures indicates the importance role of free volume in gas permeation in dry Aquivion® E8705. However, for hydrated Aquivion® E8705 the permeability less depends on hole volume.
机译:研究了Aquivion®E8705膜的邻位正电子(o-Ps)寿命和气体渗透率随温度,真空度和室温相对湿度的变化。在真空中,温度在0到100℃之间变化时,从o-Ps寿命推算出的Aquivion®E8705的孔体积逐渐增加。然而,当在室温下改变相对湿度时,孔体积基本不变。在不同温度下,O_2和H_2的渗透率对数与孔的倒数之间具有良好的线性相关性,这表明自由体积在干燥的Aquivion®E8705中对气体渗透的重要作用。但是,对于水合Aquivion®E8705,磁导率较少取决于孔的体积。

著录项

  • 来源
  • 会议地点 Smolenice Castle(SK)
  • 作者单位

    Fuel Cell Cutting-Edge Center (FC-Cubic), Technology Research Association, Koto-ku, Tokyo 135-0064, Japan,Visiting from Physics Department, Faculty of Science, Minia University, P.O. Box 61519 Minia, EGYPT;

    National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8565, JAPAN;

    Fuel Cell Cutting-Edge Center (FC-Cubic), Technology Research Association, Koto-ku, Tokyo 135-0064, Japan;

    Fuel Cell Cutting-Edge Center (FC-Cubic), Technology Research Association, Koto-ku, Tokyo 135-0064, Japan,Research Institute for Ubiquitous Energy Devices, AIST, Midorigaoka, Ikeda, Osaka 563-8577, JAPAN;

  • 会议组织
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    hole volume; gas permeation; positron annihilation; positronium; polymer electrolyte membrane; Aquivion® E8705; fuel cell;

    机译:孔体积气体渗透正电子an灭ron高分子电解质膜Aquivion®E8705;燃料电池;

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