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Positron lifetimes and mechanical properties of gamma-irradiated ultra high molecular weight polyethylene

机译:γ辐照超高分子量聚乙烯的正电子寿命和力学性能

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Positron annihilation lifetime spectroscopy (PALS) has widely been used for probing open volume defects in various materials. PALS is in principle non-destructive, yet conventional PALS is not strictly non-destructive because cutting out of two specimens from the material is required. Recently we developed a novel method of PALS, which is potentially applicable to nondestructive, onsite material inspection. In order to explore the possibility of onsite monitoring of polymer degradation by this novel method of PALS, we studied variations of positron lifetime and mechanical properties of ultra high molecular weight polyethylene (UHMWPE) subjected to γ-irradiation. Correlations were found between the mechanical properties and ortho-positronium lifetimes, suggesting the feasibility of non-destructive, onsite monitoring of polymer degradation by PALS. The effect of γ-irradiation on positronium formation is discussed.
机译:正电子an没寿命谱(PALS)已广泛用于探测各种材料中的空体积缺陷。 PALS原则上是非破坏性的,但是常规PALS并非严格非破坏性的,因为需要从材料中切出两个样本。最近,我们开发了一种新颖的PALS方法,该方法可能适用于无损现场材料检查。为了探索通过这种新颖的PALS方法现场监测聚合物降解的可能性,我们研究了受到γ辐照的超高分子量聚乙烯(UHMWPE)的正电子寿命和力学性能的变化。在机械性能和正电子寿命之间发现了相关性,这表明通过PALS对聚合物降解进行无损现场监测的可行性。讨论了γ射线对正电子形成的影响。

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