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Encapsulation of natural flavors in cyclodextrins: free volume studies by PALS

机译:天然香料在环糊精中的包封:PALS进行的自由体积研究

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Positron annihilation lifetime spectroscopy (PALS) is used to study the free-volume in P-cyclodextrin (CD) with the encapsulation of two different essential oils: garlic(Allium sativum) and marjoram (Origanum majorana). The data reveal the presence of a long lifetime component related to the o-Ps. It is observed that the addition of garlic (or marjoram) oil to β-CD results in a decrease of the o-Ps lifetime which was ascribed to a reduction of the free volume holes from 83.6 to 67.7 A~3 (79.1 to 72.6 A~3). Different mechanisms for the encapsulation of garlic and marjoram oils in P-CD are suggested by the PALS parameters.
机译:正电子an没寿命光谱法(PALS)用于研究P-环糊精(CD)中的自由体积,其中包封了两种不同的精油:大蒜(Sativum)和马郁兰(Origanum majorana)。数据表明存在与o-P相关的长寿命成分。可以看出,向β-CD中添加大蒜(或马郁兰)油会导致o-Ps寿命缩短,这归因于自由体积孔从83.6降至67.7 A〜3(从79.1降至72.6 A) 〜3)。 PALS参数提出了将大蒜油和马郁兰油包囊在P-CD中的不同机制。

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