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Comparison of Extruded Powder Metallurgy Rhenium and Hot Isostatic Pressed Rhenium

机译:粉末冶金R和热等静压hen的比较

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Rhenium is a refractory metal, but unlike other refractory metals (W, Mo, Nb, and Ta), it does not form a carbide and the crystal structure is not body-centered cubic. Rhenium has a hexagonal closed-packed crystal structure with c/a ratio of 1.615. It has a melting point of 3180 °C (second highest only to tungsten) and the third highest density of all metals at 21.04 g/cm~3. Rhenium is extremely stiff with an elastic modulus of 420 GPa (more than twice that of steel) [1]. Rhenium is immune to thermal shock and has no ductile brittle transition temperature. This material is extremely difficult to process due to a work-hardening coefficient greater than 0.5 (higher than copper) [2] and rhenium oxidizes (sublimates) in air at around 400°C [3]. Because of the high melting temperature and oxidation issues, rhenium is manufactured via powder metallurgy for large scale production; however, extremely high temperature are required for sintering and hot isostatic pressing to consolidate to sufficient density for subsequent deformation processing.
机译:hen是一种难熔金属,但与其他难熔金属(W,Mo,Nb和Ta)不同,它不会形成碳化物,并且晶体结构也不是体心立方。 hen具有c / a比为1.615的六方密堆积晶体结构。它的熔点为3180°C(仅次于钨,是第二高的),其密度为所有金属中的第三高的,为21.04 g / cm〜3。 hen的硬度极高,其弹性模量为420 GPa(是钢的两倍)[1]。 hen不受热冲击的影响,并且没有延性的脆性转变温度。这种材料由于加工硬化系数大于0.5(高于铜)而极难加工[2],并且rh在约400°C的空气中会氧化(升华)[3]。由于较高的熔化温度和氧化问题,via通过粉末冶金法进行生产,以进行大规模生产。然而,烧结和热等静压需要极高的温度,以固结至足够的密度以用于随后的变形处理。

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