Matrix Effect on Hydrogen-Atom Tunneling of Organic Molecules in Cryogenic Solids

机译：基质对低温固体中有机分子氢原子隧穿的影响

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Although the tunneling of atoms through potential energy barriers separating the reactant and reaction systems is not paid much attention in organic reactions, this plays an important role in reactions including the transfer of light atoms. Atomic tunneling is especially important for chemical reactions at low temperatures, since the thermal activation of reactant systems is very slow process in comparison with the tunneling.

机译：尽管通过有机反应将势能垒分隔反应物和反应系统的原子隧穿并没有引起多大注意，但这在包括轻原子转移在内的反应中起着重要作用。原子隧穿对于低温下的化学反应尤为重要，因为与隧道相比，反应物系统的热活化过程非常缓慢。

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《Proceedings of the 8th Japan-China bilateral symposium on radiation chemistry》|1999年|p.70-73|共4页
会议地点 Kyoto(JP);Kyoto(JP)
作者
Tsuneki Ichikawa;
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正文语种 eng
中图分类化学;
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专利

1. Matrix Effect on Hydrogen Atom Tunneling from Alkane to Free Deuterium Atoms in Cryogenic Solid [J] . Tsuneki Ichikawa, Koh-ichi Kagei, Hiroto Tachikawa, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 1999,第32期

机译：低温固体中氢从烷烃向游离氘原子的氢原子隧穿的基质效应
2. Solid H-2 versus solid noble-gas environment: Influence on photoinduced hydrogen-atom transfer in matrix-isolated 4(3H)-pyrimidinone [J] . Lapinski Leszek, Nowak Maciej J., Rostkowska Hanna The Journal of Chemical Physics . 2017,第9期

机译：固体H-2与固体贵气体环境：对基质分离的4（3H） - 嘧啶酮的光致氢原子转移的影响
3. Hydrogen-atom tunneling in isomerization around the C-O bond of 2-chloro-6-fluorophenol in low-temperature argon matrixes [J] . Nanbu S., Sekine M., Nakata M. The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2011,第35期

机译：低温氩气中2-氯-6-氟苯酚的C-O键周围异构化过程中的氢原子隧穿
4. Matrix Effect on Hydrogen-Atom Tunneling of Organic Molecules in Cryogenic Solids [C] . Tsuneki Ichikawa, Japan Atomic Energy Research Institute Japan-China bilateral symposium on radiation chemistry . 2000

机译：基质对低温固体有机分子氢原子隧穿的影响
5. Orientational and rotational motions of bacteriorhodopsin and tyrosyl peptides and proteins by time-resolved absorption and emission anisotrophy and terrylene single molecule fluourescence lifetimes in solids at room and cryogenic temperatures. [D] . Harms, Gregory S. 1998

机译：细菌视紫红质和酪氨酰肽和蛋白质的定向和旋转运动，通过时间分辨的吸收和发射各向异性和三萘嵌苯单分子在室温和低温下的固体荧光寿命而确定。
6. Molecular Electronics Special Feature: Probing charge transport at the single-molecule level on silicon by using cryogenic ultra-high vacuum scanning tunneling microscopy [O] . Nathan P. Guisinger, Nathan L. Yoder, Mark C. Hersam 2005

机译：分子电子学的特殊功能：通过使用超低温超高真空扫描隧道显微镜在硅上探测单分子水平的电荷传输
7. Organic Reaction in Cryogenic Solid. Controlling Factors for Hydrogen-Atom Abstraction. [O] . Tsuneki ICHIKAWA 1995

机译：低温固体的有机反应。氢原子抽象的控制因素。

Matrix Effect on Hydrogen-Atom Tunneling of Organic Molecules in Cryogenic Solids

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