OZONOLYSIS OF CHLOROPHENOLS AND MALEIC ACID IN AQUEOUS SOLUTION

机译：氯酚和马来酸在水溶液中的臭氧分解

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This paper discusses some results of ozone oxidation of mono-, di- and trichlorophenols in aqueous solution. The organic chlorine is converted to chloride. The yield of the resulting chloride lies between 60 and 95% of the theoretical value. Complete degradation of one mmole of chlorophenol requires 3.5-5 mmoles of ozone, which corresponds to an ozone consumption of 50-60%. The oxidation products have been found to be biodegradable. The ozone oxidation of maleic acid gave glyoxylic acid, oxalic acid, formic acid and CO_2.

机译：本文讨论了水溶液中单氯，二氯和三氯酚的臭氧氧化结果。有机氯转化为氯化物。所得氯化物的产率为理论值的60至95％。一毫摩尔氯酚的完全降解需要3.5-5毫摩尔的臭氧，这相当于50-60％的臭氧消耗量。已经发现该氧化产物是可生物降解的。马来酸的臭氧氧化得到乙醛酸，草酸，甲酸和CO_2。

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来源
《Proceedings of the Second international symposium on ozone technology》|1975年|253-261|共9页
会议地点 Montreal(CA)
作者
Ernst Gilbert;
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作者单位

Gesellschaft fuer Kernforschung, Institut fuer Radiochemie, Bereich Wasserchemie, 75 Karlsruhe, Germany;

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原文格式 PDF
正文语种 eng
中图分类氧化物和氢氧化物;
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2. Ozonolysis of organic compounds and mixtures in solution. Part I: Oleic, maleic, nonanoic and benzoic acids [J] . Deborah J. Last, Juan J. Najera, Ruth Wamsley Physical chemistry chemical physics: PCCP . 2009,第9期

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OZONOLYSIS OF CHLOROPHENOLS AND MALEIC ACID IN AQUEOUS SOLUTION

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