首页> 外文会议>Proceedings vol.2004-05; International Symposium on High Purity Silicon and Meeting of the Electrochemical Society; 20041003-08; Honolulu,HI(US) >MORPHOLOGY AND STRESS INVESTIGATIONS OF SURFACE AND SUBSURFACE REGIONS OF PLASMA HYDROGENATED AND ANNEALED CZOCHRALSKI SILICON
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MORPHOLOGY AND STRESS INVESTIGATIONS OF SURFACE AND SUBSURFACE REGIONS OF PLASMA HYDROGENATED AND ANNEALED CZOCHRALSKI SILICON

机译:等离子体加氢和退火后的直晶硅的表面和亚表面区域的形貌和应力研究

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Hydrogen plasma treatments were applied on Czochralski (Cz) silicon wafers at ~ 260 - 270 ℃ in a PECVD-setup. Those plasma treatments cause a structuring of the wafer surface regions down to the sub-100 nm scale. The thickness of the structured layers is in the order of 100 - 200 nm. The impact of the applied plasma, the doping of the substrates, and of the post-hydrogenation annealing on the morphology of the structured surface layers was studied. Annealing was applied up to 1200 ℃ in vacuum. Investigations were done by scanning electron microscopy (SEM), μ-Raman spectroscopy (μRS), and atomic force microscopy (AFM). The structuring can be explained by a redeposition mechanism. During annealing at T ≥ 800 ℃ the structured surface layers are dissolved, and Si atoms formerly located in the redeposited crystallites are rebuilt onto the wafer surface. The reconstructed wafer surface and subsurface layers exhibit strong tensile stress up to quite deep wafer regions (~ 10 μm), as was observed by depth resolved μ-Raman analysis.
机译:在PECVD装置中,在260-270℃左右的温度下,在Czochralski(Cz)硅晶片上进行了氢等离子体处理。那些等离子体处理导致晶片表面区域的结构化,直至亚100纳米以下。结构化层的厚度约为100-200nm。研究了施加的等离子体,衬底的掺杂以及加氢后退火对结构化表面层形态的影响。在真空中进行退火至1200℃。通过扫描电子显微镜(SEM),μ拉曼光谱(μRS)和原子力显微镜(AFM)进行了研究。可以通过重新沉积机制来解释结构。在T≥800℃的退火过程中,结构化的表面层被溶解,原来位于再沉积的微晶中的Si原子被重建在晶片表面上。深度分辨μ拉曼分析观察到,重建的晶片表面和亚表面层在很深的晶片区域(约10μm)内均表现出较强的拉伸应力。

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