THE EFFECT OF SURFACE SPECIES ON THE RATE OF H SORPTION INTO NANOSTRUCTURED Pd

机译：表面物种对H吸附到纳米结构Pd中的速率的影响

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Studies of the hydrogen region of nanostructured H_1-e Pd films in 1 M sulphuric acid in the presence of crystal violet, or when small amounts of Pt are deposited on to the surface, show that the adsorption of hydrogen onto the metal surface is suppressed but that at the same time the kinetics of absorption of hydrogen into the Pd to form the β-hydride are significantly enhanced suggesting that the strongly adsorbed hydrogen on the Pd surface acts as a blocking layer for absorption of hydrogen into the Pd lattice.

机译：在存在结晶紫或存在少量Pt的情况下，在1 M硫酸中对纳米结构H_1-e Pd膜的氢区域进行研究，或者当少量Pt沉积在表面上时，表明抑制了氢在金属表面上的吸附，但同时显着增强了氢吸收到Pd中以形成β-氢化物的动力学，这表明在Pd表面上强吸附的氢充当了将氢吸收到Pd晶格中的阻挡层。

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《Proceedings vol.2004-10; International Manuel M. Baizer Symposium in Honor of Dennis H. Evans and Masao Tokuda and Meeting of the Electrochemical Society; 20040509-14; San Antonio,TX(US)》|2004年|P.57-60|共4页
会议地点 San AntonioTX(US)
作者
P. N. Bartlett; J. Marwan;
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School of Chemistry, University of Southampton, Southampton, SO 17 1BJ, UK;

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原文格式 PDF
正文语种 eng
中图分类电化学、电解、磁化学;
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3. Author's response to comments by A. Lasia on the paper- Comparative effects of adsorbed S-species on H sorption into Pd from UPD and OPD; a kinetic analysis [J] . S. Y. Qian, B. E. Conway, D. Jerkiewicz International journal of hydrogen energy . 2002,第3期

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4. THE EFFECT OF SURFACE SPECIES ON THE RATE OF IISORPTION INTO NANOSTRUCTURED Pd [C] . P. N. Bartlett, J. Marwanf International Manuel M. Baizer Symposium in Honor of Dennis H. Evans and Masao Tokuda . 2004

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THE EFFECT OF SURFACE SPECIES ON THE RATE OF H SORPTION INTO NANOSTRUCTURED Pd

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