REARRANGEMENTS OF HOUSANE CATION RADICALS

机译：休烷阳离子自由基的重排

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Our quest to devise a new and novel route by which to synthesize 8-membered ring containing substances has led us to explore the chemistry of several cation radicals derived from housanes, including 17 and 23. In each instance surprising results were obtained. The role of remote substitution in governing the resioselectivity of cation radical rearrangements is discussed.

机译：我们寻求设计一种新颖且新颖的途径来合成含8元环的物质的方法，促使我们探索了衍生自丁二烯的几种阳离子自由基的化学性质，包括17和23。在每种情况下均获得了令人惊讶的结果。讨论了远程取代在控制阳离子自由基重排的选择性中的作用。

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《Proceedings vol.2004-10; International Manuel M. Baizer Symposium in Honor of Dennis H. Evans and Masao Tokuda and Meeting of the Electrochemical Society; 20040509-14; San Antonio,TX(US)》|2004年|P.1-4|共4页
会议地点 San AntonioTX(US)
作者
James B. Gerken; Alejandro Preciado; Young Sam Park; Dean J. Tantillo; R. Daniel Little;
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Department of Chemistry Biochemistry University of California, Santa Barbara Santa Barbara, California 93106;

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正文语种 eng
中图分类电化学、电解、磁化学;
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1. A Highly Selective Rearrangement of a Housane-Derived Cation Radical: An Electrochemically Mediated Transformation [J] . Young Sam Park, Selina C. Wang, Dean J. Tantillo, The Journal of Organic Chemistry . 2007,第12期

机译：Housane衍生的阳离子自由基的高度选择性重排：电化学介导的转换。
2. Remote substituent effects upon the rearrangements of housane cation radicals [J] . Gerken JB, Wang SC, Preciado AB, The Journal of Organic Chemistry . 2005,第12期

机译：远程取代基对upon烷阳离子自由基的重排影响
3. GENERATION OF 4,5-DIAZACYCLOPENTANE-1,3-DIYL RADICAL CATIONS BY CHEMICAL ELECTRON TRANSFER (CET) OXIDATION OF URAZOLE-BRIDGED BICYCLIC HOUSANES (BICYCLO[2.1.0]PENTANES) AND THEIR CHEMICAL TRANSFORMATIONS [J] . Adam W., Kammel T. The Journal of Organic Chemistry . 1996,第9期

机译：尿嘧啶桥联双环戊二烯（双环[2.1.0]五烯）的化学电子转移（CET）氧化生成4,5-二氮杂环戊烷-1,3-二基自由基
4. REARRANGEMENTS OF HOUSANE CATION RADICALS [C] . James B. Gcrken, Alejandro Preciado, Young Sam Park, International Manuel M. Baizer Symposium in Honor of Dennis H. Evans and Masao Tokuda . 2004

机译：屋面阳离子自由基重排
5. Experimental and computational investigations of substituent effects on housane cation radical rearrangement, intramolecular atom transfer reactions of trimethylenemethane diradicals, and kinetic isotope effects on alkylidene carbene insertion reactions. [D] . Gerken, James Beall. 2004

机译：实验和计算研究的取代基对husane阳离子自由基重排的影响，三亚甲基二自由基的分子内原子转移反应以及动力学同位素对亚烷基卡宾插入反应的影响。
6. Facile Smiles-type rearrangement in radical cations of N-acyl arylsulfonamides and analogs [O] . Karl K. Irikura, Nino G. Todua -1

机译：N-酰基芳基磺酰胺和类似物的自由基阳离子中的简易Smiles型重排
7. A Highly Selective Rearrangement of a Housane-Derived Cation Radical: An Electrochemically Mediated Transformation [O] . -1

机译：高度选择性重排尿囊阳离子：一种电化学介导的转化

REARRANGEMENTS OF HOUSANE CATION RADICALS

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