EXPERIMENTAL PROOF OF FORMATION OF IMINES AS INTERMEDIATES IN THE REDUCTION OF HYDRAZONES

机译：还原肼类中间体的矿物质形成的实验证明

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Imines derived from fluorenone do not undergo at pH 6-10 rapid hydrolysis. In this pH-range the imine is reduced in two one-electron steps. The fluorenone hydrazone and the corresponding N,N,N-trimethylhydrazonium ion is reduced in two steps: In the first three-electron step the two-electron cleavage of the N-N bond occurs. This wave is practically overlapped by the first one-electron wave of the imine. In the second one-electron wave the second reduction process of the imine takes place. This finding represents an experimental proof demonstrating that in hydrazones the N-N bond is cleaved first.

机译：衍生自芴酮的亚胺在pH 6-10时不会快速水解。在此pH范围内，亚胺在两个单电子步骤中被还原。分两个步骤还原芴酮和相应的N，N，N-三甲基hydr离子：在第一个三电子步骤中，发生N-N键的两电子裂解。该波实际上被亚胺的第一单电子波重叠。在第二单电子波中，发生亚胺的第二还原过程。这一发现代表了一个实验证据，表明在azo中，N-N键首先被裂解。

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《Proceedings vol.2004-10; International Manuel M. Baizer Symposium in Honor of Dennis H. Evans and Masao Tokuda and Meeting of the Electrochemical Society; 20040509-14; San Antonio,TX(US)》|2004年|P.169-172|共4页
会议地点 San AntonioTX(US)
作者
M.S. Baymak; H. Lund; P. Zuman;
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Department of Chemistry, Clarkson University, Potsdam, NY, 13699-5810, USA;

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正文语种 eng
中图分类电化学、电解、磁化学;
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1. Experimental evidence of formation of imines in the course of reduction of hydrazones [J] . Baymak MS, Celik H, Lund H, Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 2005,第2期

机译：还原过程中亚胺形成的实验证据
2. Experimental Analysis of the Catalytic Cycle of the Borane-Promoted Imine Reduction with Hydrosilanes: Spectroscopic Detection of Unexpected Intermediates and a Refined Mechanism [J] . Julia Hermeke, Marius Mewald, Martin Oestreich Journal of the American Chemical Society . 2013,第46期

机译：氢硅烷催化硼烷促进的亚胺还原催化循环的实验分析：意外中间体的光谱检测和精细机理
3. Generation of NH-azomethine imine intermediates through the 1,2-hydrogen shift of hydrazones and their intermolecular cycloaddition reaction with olefinic dipolarophiles [J] . Noguchi M., Matsumoto S., Shirai M., Tetrahedron . 2003,第23期

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4. EXPERIMENTAL PROOF OF FORMATION OF IMINES AS INTERMEDIATES IN THE REDUCTION OF HYDRAZONES [C] . M. S. Baymak, H. Lund, P. Zuman International Manuel M. Baizer Symposium in Honor of Dennis H. Evans and Masao Tokuda . 2004

机译：亚胺中含量中间体形成的实验证据
5. Nitrate reduction and methane formation as influenced by iron-centered intermediate redox processes in rice soils. [D] . Huang, Bin. 2005

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6. Evidence of a sequestered imine intermediate during reduction of nitrile to amine by the nitrile reductase QueF from Escherichia coli [O] . Jihye Jung, Bernd Nidetzky 2018

机译：大肠杆菌腈还原酶QueF将腈还原成胺的过程中存在螯合亚胺中间体的证据
7. A relative PCF-definability result for strongly stable functions and some corollaries (Extended abstract)⋆⋆The results presented in this extended abstract have already been published in Information and Computation, under the same title. From this original article 10, we have kept all the informal discussions, the statements of the main results as well as those of the intermediate lemmas, but most proofs have been suppressed. [O] . Ehrhard Thomas 2000

机译：相对PCF的可定义性结果，用于高度稳定的功能和某些推论（扩展摘要）⋆extended本扩展摘要中呈现的结果已经以相同的标题发布在《信息与计算》上。从原始文章10开始，我们保留了所有非正式讨论，主要结果的陈述以及中间引理的陈述，但大多数证据都被压制了。
8. Imine Bridged Planar Poly(p-phenylene) Derivatives for Maximization of Extended p-Conjugation. The Common Intermediate Approach [R] . Lamba, J. J., Tour, J. M. 1995

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EXPERIMENTAL PROOF OF FORMATION OF IMINES AS INTERMEDIATES IN THE REDUCTION OF HYDRAZONES

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