Vaporization Processes and Thermodynamic Properties of Oxide Systems Studied by High Temperature Mass Spectrometry

机译：高温质谱研究氧化物体系的汽化过程和热力学性质

获取原文

获取原文并翻译 | 示例

页面导航

摘要
著录项
相似文献
相关主题

摘要

Information on the vaporization processes and thermodynamic properties of the ternary silicate systems Na_2O-B_2O_3-SiO_2, Cs_2O-B_2O_3-SiO_2, RB_2O-B_2O_3-SiO_2, MgO-B_2O_3-SiO_2, CaO-B_2O_3-SiO_2, SrO-B_2O_3-SiO_2, BaO-B_2O_3-SiO_2, MgO-Al_2O_3-SiO_2, CaO-Al_2O_3-SiO_2, CaO-TiO_2-SiO_2, BaO-TiO_2-SiO_2, PbO-B_2O_3-SiO_2 and ZnO-B_2O_3-SiO_2 together with previously obtained data is discussed. Various types of vapour species were found over the oxide systems studied such as the associated, dissociated and polymerized products of vaporization. The systematic trends in the vaporization of binary and multicomponent oxide systems are illustrated and discussed from the point of view of the acid-base concept. Results on determination of thermodynamic functions in oxide systems were considered taking into account the main requirements for the confirmation of their reliability. The general lattice theory of associated solutions was used for the calculation of thermodynamic properties of the ternary silicate melts studied. Some industrial applications of multicomponent oxide systems are also illustrated.

机译：三元硅酸盐体系Na_2O-B_2O_3-SiO_2，Cs_2O-B_2O_3-SiO_2，RB_2O-B_2O_3-SiO_2，MgO-B_2O_3-SiO_2，CaO-B_2O_3-SiO2，SrO-B_2O_3-SiO_2，BaO的汽化过程和热力学性质的信息讨论了-B_2O_3-SiO_2，MgO-Al_2O_3-SiO_2，CaO-Al_2O_3-SiO_2，CaO-TiO_2-SiO_2，BaO-TiO_2-SiO_2，PbO-B_2O_3-SiO_2和ZnO-B_2O_3-SiO_2以及先前获得的数据。在所研究的氧化物体系中发现了各种类型的蒸气，例如伴生的，离解的和聚合的汽化产物。从酸碱概念的角度说明并讨论了二元和多组分氧化物体系的汽化的系统趋势。考虑了确定氧化物系统热力学函数的结果，并考虑到确认其可靠性的主要要求。关联溶液的一般晶格理论用于计算所研究的三元硅酸盐熔体的热力学性质。还说明了多组分氧化物体系的一些工业应用。

著录项

来源
《Proceedings of the workshop on knudsen effusion mass spectrometry》|2012年|55-67|共13页
会议地点 Julich(DE)
作者
V.L. Stolyarova;
展开▼
作者单位

Department of Chemistry, Saint Petersburg State University, Saint Petersburg 198504,Russian Federation;

展开▼
会议组织
原文格式 PDF
正文语种 eng
中图分类
关键词

相似文献

外文文献
中文文献
专利

1. VAPORIZATION FEATURES OF OXIDE SYSTEMS STUDIED BY HIGH-TEMPERATURE MASS SPECTROMETRY [J] . Stolyarova V. Journal of Nuclear Materials: Materials Aspects of Fission and Fusion . 1997,第0期

机译：高温质谱法研究氧化物体系的汽化特性
2. High-temperature mass spectrometric study of the vaporization processes and thermodynamic properties in the Gd2O3-Y2O3-HfO2 system [J] . Kablov Eugene N., Stolyarova Valentina L., Lopatin Sergey I., Rapid Communications in Mass Spectrometry: RCM . 2017,第13期

机译：GD203-Y2O3-HFO2系统中汽化过程和热力学性能的高温质谱研究
3. High-temperature mass spectrometric study of the vaporization processes and thermodynamic properties of melts in the PbO-B_2O_3- SiO_2 system [J] . Stolyarova V.L., Lopatin S.I., Shilov A.L., Rapid Communications in Mass Spectrometry: RCM . 2013,第13期

机译：PbO-B_2O_3- SiO_2系统中熔体的汽化过程和热力学性质的高温质谱研究
4. Vaporization Processes and Thermodynamic Properties of Oxide Systems Studied by High Temperature Mass Spectrometry [C] . V. L. Stolyarova Workshop on Knudsen Effusion Mass Spectrometry . 2013

机译：高温质谱法研究氧化物系统的汽化过程和热力学性能
5. Thermodynamic properties and vaporization phenomena of oxide systems including calcium oxide, magnesium oxide, calcium zirconium oxide, strontium zirconium oxide, and barium zirconium oxide [D] . Gourishankar, Karthick V. 1993

机译：氧化物体系的热力学性质和汽化现象，包括氧化钙，氧化镁，氧化钙锆，锶氧化锆和钡锆氧化物
6. FAD roles in glucose catalytic oxidation studied by multiphase flow of extractive electrospray ionization (MF-EESI) mass spectrometry [O] . Yan Wang, Min Sun, Jinping Qiao, 2018

机译：萃取电喷雾电离（MF-EESI）质谱多相流研究FAD在葡萄糖催化氧化中的作用
7. High Temperature Mass Spectrometric Study of Thermodynamic Properties and Vaporization Processes of Oxide Systems: Experiment and Modeling [O] . V.L. Stolyarova 2013

机译：高温质谱研究氧化物系统热力学性能和汽化过程：实验与建模
8. Congruent Vaporization in the V-Si System as Studied by High Temperature Knudsen Cell Mass Spectrometry [R] . Myers, C. E., Kematick, R. J. 1985

机译：高温克努森细胞质谱研究V-si体系中的一致蒸发

Vaporization Processes and Thermodynamic Properties of Oxide Systems Studied by High Temperature Mass Spectrometry

摘要

著录项

相似文献

相关主题

期刊订阅