Determination of the dissociation energy of Diatomic Molecules by KEMS (Knudsen Effusion Mass Spectrometry): intragroup 14 and group 11-group 2 molecules

机译：用KEMS（Knudsen扩散质谱）测定双原子分子的解离能：第14组内和第11组2组分子

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This contribution summarize our recent work devoted to detect and thermochemically characterise by KEMS experiments (Knudsen Effusion Mass Spectrometry) a number of diatomic gaseous molecules either never observed before or whose bond energy was unknown. The results obtained over the years for the intragroup 14 and the group 11-group 2 species are here collected and compared with quantum chemical calculations at the CCSD(T) level.

机译：这一贡献总结了我们最近的工作，该工作致力于通过KEMS实验（努森渗出质谱）检测和热化学表征许多双原子气态分子，这些分子以前从未发现过，或者其键能未知。多年来收集的第14组内物种和第11组-第2组物种的结果在此收集，并与CCSD（T）级的量子化学计算进行比较。

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《Proceedings of the workshop on knudsen effusion mass spectrometry》|2012年|99-111|共13页
会议地点 Julich(DE)
作者
A. Ciccioli; G. Gigli;
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Dipartimento di Chimica, Sapienza Universita di Roma, p.le A.Moro 5, 00185 Roma, Italy;

Dipartimento di Chimica, Sapienza Universita di Roma, p.le A.Moro 5, 00185 Roma, Italy;

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专利

1. Development of lithium attachment mass spectrometry - knudsen effusion and chemical ionisation mass spectrometry (KEMS, CIMS) [J] . Booth A. Murray, Bannan Thomas J., Benyezzar Med, The Analyst: The Analytical Journal of the Royal Society of Chemistry: A Monthly International Publication Dealing with All Branches of Analytical Chemistry . 2017,第19期

机译：锂附着质谱的研制 - Knudsen积分和化学电离质谱（KEMS，CIMS）
2. Experimental and computational investigation of the group 11-group 2 diatomic molecules: First determination of the AuSr and AuBa bond energies and thermodynamic stability of the copper- and silver-alkaline earth species [J] . Ciccioli A., Gigli G., Lauricella M. The Journal of Chemical Physics . 2012,第18期

机译：实验和计算研究的第11组2组双原子分子：首次确定了铜和银碱性地球物种的AuSr和AuBa键能以及热力学稳定性
3. Investigations at High Temperature in Both Equilibrium and Kinetic Statewith Knudsen Effusion Mass Spectrometry (KEMS) and a SkimmerIntegrated Coupling System of Mass Spectrometer and Thermal Analysis(STAMS) [J] . Dietmar Kobertz, Christo Guguschev, Michael Muller The Open Thermodynamics Journal . 2013,第1期

机译：使用Knudsen扩散质谱（KEMS）和撇油器集成的质谱仪与热分析（STAMS）耦合系统在平衡和动力学状态下进行高温研究
4. Determination of the dissociation energy of Diatomic Molecules by KEMS (Knudsen Effusion Mass Spectrometry): intragroup 14 and group 11-group 2 molecules [C] . A. Ciccioli, G. Gigli Workshop on Knudsen Effusion Mass Spectrometry . 2013

机译：KEMS（Knudsen积分质谱法测定硅藻分子的解离能）：Intragrous 14和11组分子
5. Determination of bond dissociation energies using Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry. [D] . Yang, Yarjing. 1996

机译：使用傅立叶变换离子回旋共振（FT-ICR）质谱法测定键解离能。
6. Rapid determination of antioxidant molecules in volatiles of rose tea by gas chromatography–mass spectrometry combined with DPPH reaction [O] . Hao Qin, Bao-cai Li, Wei-feng Dai, 2019

机译：通过气相色谱 - 质谱与DPPH反应结合玫瑰茶挥发物中抗氧化分子的快速测定
7. Determination of the dissociation energy of Diatomic Molecules by KEMS (Knudsen Effusion Mass Spectrometry): intragroup 14 and group 11-group 2 molecules [O] . A. Ciccioli, G. Gigli 2016

机译：通过KEms（Knudsen Effusion质谱法）测定双原子分子的解离能：第14族和第11族第2族分子

Determination of the dissociation energy of Diatomic Molecules by KEMS (Knudsen Effusion Mass Spectrometry): intragroup 14 and group 11-group 2 molecules

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