Experimental Thermodynamics of New Electrode Materials for Li-Ion Batteries

机译：锂离子电池新电极材料的实验热力学

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Vaporization of five liquid binary Li-Sn alloys (molar fractions x_(Li) = 0.1; 0.2; 0.3; 0.4; and 0.5) as well as pure Li have been investigated in the temperature range 576-1040 K by Knudsen effusion mass spectrometry (KEMS). The Thermodynamic activity of lithium was determined by the ratio of ion current intensities measured over the alloy and the pure metal. The activity of tin was determined by Gibbs-Duhem integration. The results were approximated by Redlich-Kister sub-regular solution model and compared with the available literature data.

机译：通过Knudsen渗流质谱法研究了五种液态二元Li-Sn合金（摩尔分数x_（Li）= 0.1; 0.2; 0.3; 0.4; 0.5）的汽化以及纯Li在576-1040 K温度范围内的汽化（ KEMS）。锂的热力学活性由在合金和纯金属上测得的离子电流强度之比确定。锡的活性通过Gibbs-Duhem积分确定。通过Redlich-Kister次正规解模型对结果进行近似，并与可用的文献数据进行比较。

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《Proceedings of the workshop on knudsen effusion mass spectrometry》|2012年|303-312|共10页
会议地点 Julich(DE)
作者
D. Henriques; V. Motalov; L. Bencze; T. Markus;
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Institute for Energy and Climate Research (IEK-2), Forschungszentrum Juelich GmbH,D-52425 Juech, Germany;

Institute for Energy and Climate Research (IEK-2), Forschungszentrum Juelich GmbH,D-52425 Juech, Germany,Department of Physics, Ivanovo State University of Chemistry Technology, Engels av.7, 153000 Ivanovo, Russia;

Institute for Energy and Climate Research (IEK-2), Forschungszentrum Juelich GmbH,D-52425 Juech, Germany,Eoetvoes Lorand University, Dept. of Physical Chemistry, H-1107 Budapest, Pazmany Peter setany 1/A, Hungary;

Institute for Energy and Climate Research (IEK-2), Forschungszentrum Juelich GmbH,D-52425 Juech, Germany;

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Experimental Thermodynamics of New Electrode Materials for Li-Ion Batteries

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