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Plasma chemical synthesis of fine MoSi_2 and MoSi_2-Si_3N_4 composite powders

机译:MoSi_2和MoSi_2-Si_3N_4复合粉末的等离子体化学合成

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The preparation of fine MoSi_2 and MoSi_2-Si_3N_4 composite powders with specific surface area of 16-33 and 30-41 m~2/g respectively by evaporation of Si and Mo raw powder mixtures or coarse grained MoSi_2 in radio frequency inductively coupled nitrogen plasma flow was investigated. Specific surface area of obtained powders as well as content of MoSi_2 modifications, Si_3N_4 and extra phases Mo_5Si_3, Si depend on the raw powder feeding rate, the cooling gas flow rate and the composition of raw mixtures. The shape of the product particles was spherical for MoSi_2 and both spherical and whiskers for composites.
机译:通过在射频感应耦合氮等离子体流中蒸发Si和Mo粗粉混合物或粗粒MoSi_2来制备比表面积分别为16-33和30-41 m〜2 / g的细MoSi_2和MoSi_2-Si_3N_4复合粉末被调查了。所获得的粉末的比表面积以及MoSi_2修饰物Si_3N_4和额外的相Mo_5Si_3,Si的含量取决于原料粉末的进料速度,冷却气体流速和原料混合物的组成。对于MoSi_2,产物颗粒的形状为球形,对于复合材料,产物颗粒的形状为球形和晶须形。

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