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BOUND WATER CONTENT, PERMEABILITY AND RESIDUAL COMPRESSIVE STRENGTH OF CONCRETE AT HIGH TEMPERATURES

机译:高温下混凝土的束缚水含量,渗透率和残余抗压强度

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Concrete damage by high temperatures includes weight loss, strength and modulus reductions and the formation of cracks and large pores. Thermal treatment reduces the amount of chemically bound water in the hydrate phase. A rise in temperature affects the pore structure by reducing the specific surface of hydration products. Cement paste becomes more heterogeneous in microstructure and coarser in pore structure. This reveals in higher pore median radius, total porosity and volume of large pores in a weight unit of hydrated cement paste of concrete. Compressive strength is not only significant parameter showing structural integrity of concrete; permeability influences concrete durability as well. To demonstrate this, permeability coefficients at various high temperatures are presented. The key quantitative insight into the hydrate phase decomposition is based on thermal analysis results. Thermo gravimetric (TG) mass losses are related to the hydrate phase changes. The tests employing TG mass losses answer the question if the hydrate phase is present at individual high-temperature levels and what its quantitative state is. Strength estimations and methods of pore intrusion porosimetry with calculated permeability coefficients and thermal analysis are suitable for the interpretation of concrete behaviour when subjected to high-temperature attack. Conclusions are drawn about residual properties of concrete specimens from Temelin (Czech Republic), Mochovce (Slovakia) and Penly (France) nuclear power plant (NPP); when subjected to temperatures up to 800℃. Relations among compressive strength, permeability, pore median radius and bound water content in concretes are discussed and concrete resistance with various mixture compositions is compared.
机译:高温对混凝土的破坏包括重量损失,强度和模量降低以及裂缝和大孔的形成。热处理减少了水合物相中化学结合的水量。温度升高通过降低水合产物的比表面积来影响孔结构。水泥浆在微观结构上变得更加不均匀,在孔隙结构上变得更加粗糙。这表明,以水合水泥糊料的重量单位计,孔隙中值半径,总孔隙率和大孔隙的体积更大。抗压强度不仅是显示混凝土结构完整性的重要参数,而且还具有抗压强度。渗透性也会影响混凝土的耐久性。为了证明这一点,提出了各种高温下的渗透系数。水合物相分解的关键定量见解基于热分析结果。热重(TG)质量损失与水合物相变有关。使用TG质量损失的测试回答了以下问题:水合物相是否存在于各个高温水平下以及其定量状态是什么。具有计算的渗透系数和热分析的强度估算和孔隙侵入孔隙率法,适用于解释遭受高温侵蚀时的混凝土行为。得出了来自Temelin(捷克共和国),Mochovce(斯洛伐克)和Penly(法国)核电站(NPP)的混凝土标本的残余性能的结论;当温度高达800℃时。讨论了混凝土的抗压强度,渗透率,孔隙中值半径和结合水含量之间的关系,并比较了各种混合料的混凝土抗力。

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