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Retardation of various nitroaromatic compounds in highly permeable aquifers

机译:高渗透性含水层中各种硝基芳族化合物的阻滞作用

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Groundwater in the discharge area of former ammunition production facilities often reveals severe contamination by production residues and waste products. Thus, these can cause health hazard to human beings in case untreated water is consumed. The investigation of the WASAG explosives plant in Haltern, Germany, revealed lack of scientific knowledge about retardation of nitroaromatic compounds. In this case study we have to deal with a more than 1.65 km elongated contamination plume consisting of various nitroaromatic compounds such as trinitrotoluene, dinitrotoluenes, dinitrobenzens, dinitronaphthenes and various degradation compounds coming from a former production area used for military production during times of war. There, from 1918 until 1922 waste waters from dismantling ammunition were sunk into a deep-reaching extended aquifer of high permeability. Therefore, a laboratory investigation program with column tests was initiated. First results reveal that retention and release processes as well as degradation mechanisms play a considerable role determining the velocity of transportation of contaminants. There is a strong correlation of the retardation coefficients of the nitroaromates with the content of silt, clay and organic substances in the soil. Even very small contents of these substances cause a significant increase of retardation factors. Also, the retardation factors of different nitroaromatic compounds vary in a wide range.
机译:以前的弹药生产设施的排放区中的地下水经常显示出生产残留物和废品造成的严重污染。因此,如果食用未经处理的水,可能会对人类健康造成危害。对德国Haltern的WASAG炸药厂的调查显示,缺乏有关阻滞硝基芳族化合物的科学知识。在本案例研究中,我们必须处理一个超过1.65公里的拉长的污染羽,其中包括各种硝基芳族化合物,例如三硝基甲苯,二硝基甲苯,二硝基苯,二硝基环烷和各种降解化合物,这些化合物来自战争期间用于军事生产的先前生产地区。从1918年到1922年,分解弹药的废水在那里沉入了深层的高渗透性高含水层中。因此,启动了带有柱测试的实验室研究计划。初步结果表明,保留和释放过程以及降解机理在决定污染物运输速度方面起着相当重要的作用。硝基芳族化合物的阻滞系数与土壤中淤泥,粘土和有机物的含量密切相关。这些物质的含量即使很小,也会显着增加延迟因子。另外,不同的硝基芳族化合物的延迟因子在宽范围内变化。

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