ELECTROCHEMICAL REDUCTION OF FORMALDEHYDE TO ETHYLENE GLYCOL AT MODIFIED GRAPHITE ELECTRODES

机译：修饰石墨电极上甲醛的电化学还原成乙二醇

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The electrochemical reduction of formaldehyde to ethylene glycol has been investigated with boron-doped diamond film coated graphite electrodes. The boron-doped diamond films were deposited using a high-pressure microwave plasma-assisted chemical vapor deposition system. The film was continuous and uniform. Raman spectroscopy revealed a high degree of sp3 bonding in the film. The coated electrodes possessed a wider working potential window and lower capacitive current than the bare electrode. The coated electrode also showed superior stability for the generation of ethylene glycol by electrochemical reduction of formaldehyde, as compare to the bare graphite electrode.

机译：用硼掺杂的金刚石薄膜涂覆的石墨电极已经研究了甲醛将电化学还原成乙二醇的方法。使用高压微波等离子体辅助化学气相沉积系统沉积掺硼金刚石薄膜。该膜是连续且均匀的。拉曼光谱显示膜中高度的sp3键合。与裸电极相比，涂覆电极具有更大的工作电势窗口和更低的电容电流。与裸露的石墨电极相比，该涂层电极还显示出通过电化学还原甲醛来生成乙二醇的优异稳定性。

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《The Seventh International Symposium on Diamond Materials was Held at the 200th Meeting of the Electrochemical Society, Jointly with the 52nd Meeting of the International Society of Electrochemistry, Sep 2-7, 2001, San Francisco, California》|2001年|p.185-191|共7页
会议地点 San Francisco CA(US);San Francisco CA(US);San Francisco CA(US)
作者
Fabrice Regisser; Greg M. Swain; Daniel Belanger;
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作者单位

Departement de Chimie, Universite du Qu6bec a Montreal, Case Postale 8888, succursale Centre-Ville, Montreal (Quebec) Canada, H3C 3P8;

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正文语种 eng
中图分类化学;
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1. Electrochemical reduction of CO2 to ethylene glycol on imidazolium ion-terminated self-assembly monolayer-modified Au electrodes in an aqueous solution [J] . Tamura Jun, Ono Akihiko, Sugano Yoshitsune, Physical chemistry chemical physics: PCCP . 2015,第39期

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2. Amperometric detection of periodate using a graphite electrode modified with a novel alpha-Keggin-type silicotungstic acid salt and determination of ethylene glycol in antifreeze fluids [J] . Prodromidis MI., Efstathiou CE., Karayannis MI., Electroanalysis . 2001,第11期

机译：使用新型α-Keggin型硅钨酸盐修饰的石墨电极对高碘酸盐进行安培检测，并测定防冻液中的乙二醇
3. Electrochemical degradation of formaldehyde with a novel Pd/GO modified graphite electrode [J] . Qing Hao, Yonggang Zhang International Journal of Electrochemical Science . 2016,第2期

机译：新型Pd / GO修饰石墨电极对甲醛的电化学降解
4. Electrochemical reduction of formaldehyde to ethylene glycol at modified graphite electrodes [C] . Fabrice Regisser, Greg M. Swain, Daniel Belanger International symposium on Diamond Materials . 2002

机译：改性石墨电极在乙二醇中的电化学还原
5. Electrodes Modified With Molecular Catalysts for the Electrochemical Reduction of CO2 to Co [D] . Zhanaidarova, Almagul. 2019

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ELECTROCHEMICAL REDUCTION OF FORMALDEHYDE TO ETHYLENE GLYCOL AT MODIFIED GRAPHITE ELECTRODES

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