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Structural Relaxation Enhanced by Impurities in Silica Glass

机译:石英玻璃中的杂质增强结构弛豫

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摘要

Effects of OH on the structural relaxation in silica glass were investigated by observing the fictive temperature, which was determined from the position of infrared absorption peak around 2260 cm~(-1) related to the average Si-O-Si bond angle. It has been found that OH strongly reduces the relaxation time of the a-relaxation, while it slightly decreases its activation energy. Moreover, OH generates a sub-relaxational process. Its relaxation time decreases with increasing the OH concentration.
机译:通过观察虚构温度来研究OH对石英玻璃结构弛豫的影响,该虚构温度是由与平均Si-O-Si键角有关的2260 cm〜(-1)附近的红外吸收峰的位置确定的。已经发现,OH极大地减少了α-松弛的弛豫时间,同时它稍微降低了其活化能。而且,OH产生亚松弛过程。随着OH浓度的增加,其弛豫时间减少。

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