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Dynamics of Liquid-Glass Transition in Propanol

机译:丙醇中液-玻璃转变的动力学

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摘要

The multiple dynamics using dielectric spectroscopy on n-propanol (nP) have already been published, but the origins of each process are open problems yet. According to the Hansen's analysis on the lineshape of nP, 3 different relaxation modes were classified: a slow Debye-type relaxation process, the #alpha#-relaxation process whose relaxation frequency well matches those of the viscosity, PCS and Brillouin results and the Johari-Goldstein type #beta#-relaxation process. In the present paper we followed this analysis on nP and extended the experimental materials to i-propanol (iP) and their deuterated ones, nP-d1 and iP-d1, to clarify the role of hydrogen bonding and the structural effect of the dielectric dynamics.
机译:在正丙醇(nP)上使用介电谱的多重动力学已经发表,但是每个过程的起源仍然是未解决的问题。根据Hansen对nP线形的分析,分类了3种不同的弛豫模式:慢Debye型弛豫过程,#α#弛豫过程,其弛豫频率与粘度,PCS和布里渊结果以及Johari -Goldstein型#beta#松弛过程。在本文中,我们对nP进行了这种分析,并将实验材料扩展到异丙醇(iP)及其氘代化合物nP-d1和iP-d1,以阐明氢键的作用和介电动力学的结构效应。

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