首页> 外文会议>Sol-Gel Methods for Materials Processing: Focusing on Materials for Pollution Control, Water Purification, and Soil Remediation >SYNTHESIS, STRUCTURE AND ADSORPTION PROPERTIES OF HEXAGONALLY ORDERED MESOPOROUS ORGANOSILICAS FUNCTIONALIZED WITH SULFUR-CONTAINING GROUPS
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SYNTHESIS, STRUCTURE AND ADSORPTION PROPERTIES OF HEXAGONALLY ORDERED MESOPOROUS ORGANOSILICAS FUNCTIONALIZED WITH SULFUR-CONTAINING GROUPS

机译:含硫基团功能六方介孔有机硅的合成,结构和吸附性能

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SBA-15 mesoporous organosilicas with the p6m symmetry were synthesized by sol-gel co-condensation of tetraethyl orthosilicate with merca-ptopropyltriethoxysilane, bis[3-(ethoxysilyl)propyl]ethane, bis[3-(ethoxy-silyl) propyl]disulfide, and bis[3-(ethoxysilyl)propyl]tetrasulfide. Final samples were characterized by X-ray diffraction and nitrogen sorption measurements. Depending on the monomers used, the resulted materials exhibit well or poorly ordered structures. All materials have a well-developed porous structure and high content of sulfur-containing moieties introduced by co-condensation.
机译:通过原硅酸四乙酯与巯基丙基三乙氧基硅烷,双[3-(乙氧基甲硅烷基)丙基]乙烷,双[3-(乙氧基甲硅烷基)丙基]二硫化物的溶胶-凝胶共缩合反应合成具有p6m对称性的SBA-15介孔有机二氧化硅。和双[3-(乙氧基甲硅烷基)丙基]四硫化物。通过X射线衍射和氮吸附测量来表征最终样品。取决于所使用的单体,所得材料表现出良好或不良的结构。所有材料均具有发达的多孔结构和通过共缩合引入的高含量含硫部分。

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