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SELECTED CONTEMPORARY TOPICS IN SOL-GEL ELECTRO-CHEMISTRY

机译：溶胶-凝胶电化学中的选定当代主题

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摘要

This review provides an overview of some exciting, new as well as somewhat older, directions in sol-gel electrochemical applications of silicates and composite silicate electrodes. Rather than provide an exhaustive account of all the many papers that have been published on sol-gel electrochemistry and composite sol-gel electrodes, we prefer to illustrate the versatility of sol-gel chemistry by a few select examples which on the one hand illustrate the power entailed in sol-gel technology for electrochemical applications, and on the other hand point to hot electrochemical fields in which more research is due and exciting developments are to be expected. We start this review with a brief historical perspective. The inorganic sol-gel and silicone electrochemistry fields are both rather old though never extensively dealt with particularly when it comes to sensing applications. In contrast, the sol-gel electrochemistry of inorganic-organic hybrids is a relatively young field whose importance was recognized only in the last 30 years, and despite, or maybe even owing to the late recognition it is being very extensively studied nowadays. The use of composite electrodes for sensing and other applications is emphasized in this review, and the fast evolving electrodriven deposition techniques are reviewed.
机译：这篇综述概述了硅酸盐和复合硅酸盐电极在溶胶-凝胶电化学应用中的一些令人兴奋的，新的以及有些古老的方向。与其提供详尽的关于溶胶-凝胶电化学和复合溶胶-凝胶电极的所有论文的详细信息，我们不希望通过一些示例来说明溶胶-凝胶化学的多功能性，这些示例一方面说明了溶胶-凝胶技术在电化学领域的应用带来了巨大的动力，另一方面，热的电化学领域也有待进一步研究，并且有望获得令人兴奋的发展。我们从简短的历史角度开始这篇评论。无机溶胶-凝胶和有机硅电化学领域都比较老，尽管从未广泛涉及，特别是在传感应用方面。相比之下，无机-有机杂化物的溶胶-凝胶电化学是一个相对较年轻的领域，其重要性仅在最近30年才被认识到，尽管，或者甚至由于较晚的认识，如今它仍在被广泛研究。在这篇评论中强调了复合电极在传感和其他应用中的使用，并对快速发展的电驱动沉积技术进行了评论。

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