首页> 外文会议>Solid State Lasers and Amplifiers II >Growth and non critical phase matching second harmonic generation of Gd_(1-x)R_xCa_4O(BO_3)_3 (R = Sc or Lu) nonlinear crystals
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Growth and non critical phase matching second harmonic generation of Gd_(1-x)R_xCa_4O(BO_3)_3 (R = Sc or Lu) nonlinear crystals

机译:Gd_(1-x)R_xCa_4O(BO_3)_3(R = Sc或Lu)非线性晶体的生长和非关键相位匹配二次谐波生成

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Single crystals of Gd_(1-x)R_xCa_4O(BO_3)_3 (R~(3+) = Sc~(3+) or Lu~(3+)) with large size and good quality have been grown by Czochralski method. By changing the compositional parameter x of Gd_(1-x)Sc_xCa_4O(BO_3)_3 and Gd_(1-x)Lu_xCa_4O(BO_3)_3 crystals, their optical birefringence can be controlled in order to achieve non critical phase matching (NCPM) in the ranges of 792 - 824 nm along Y axis and 922 - 963 nm along Z axis, during second harmonic generations (SHG). The chemical compositions of the grown crystals were determined and X-ray diffraction measurements have been carried out to characterize the structural changes with compositional parameter x. The solubility limits of R~(3+) ions in the Gd_4Ca_4O(BO_3)_3 crystals were also determined. Nonlinear optical properties of these new biaxial borate crystals are reported. Experimental determinations of doubled frequencies in NCPM conditions are in good agreement with theoretical predictions.
机译:用Czochralski法生长了尺寸大,质量好的Gd_(1-x)R_xCa_4O(BO_3)_3(R〜(3+)= Sc〜(3+)或Lu〜(3+))单晶。通过更改Gd_(1-x)Sc_xCa_4O(BO_3)_3和Gd_(1-x)Lu_xCa_4O(BO_3)_3晶体的成分参数x,可以控制它们的光学双折射以实现非临界相位匹配(NCPM)。在二次谐波产生(SHG)期间,沿Y轴的792-824 nm和沿Z轴的922-963 nm的范围。确定了生长晶体的化学组成,并进行了X射线衍射测量以表征具有组成参数x的结构变化。还确定了R〜(3+)离子在Gd_4Ca_4O(BO_3)_3晶体中的溶解度极限。这些新的双轴硼酸盐晶体的非线性光学性质已报道。 NCPM条件下双倍频率的实验确定与理论预测吻合良好。

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