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Photoconductivity of diamond-like carbon

机译:类金刚石碳的光电导性

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摘要

We have studied the photoconductivity in pure tetrahedral amorphous carbon (ta-C) and hydrogenated tetrahedral amorphous carbon (ta-C:H). Good photoconductive properties are demonstrated for ta-C:H, showing that the hydrogenated form of ta-C is of a higher electronic quality. Transport and recombination parameters are derived. Ta-C:H are low mobility solids with a mu tau product of the order of 10~(-12) cm~2V~(-1) and a recombination time tau _r of about 10~(-7) s. At low energy excitation, the photoconductivity shows a sublinear dependence on the light intensity over a wide temperature range. The relationship between the photoconductivity and the density of spin defect centers is discussed. UV light is used to excite carriers into the extended states. Competitive recombination centers may be involved at high excitation energy.
机译:我们研究了纯四面体无定形碳(ta-C)和氢化四面体无定形碳(ta-C:H)中的光电导性。 ta-C:H具有良好的光电导性能,表明ta-C的氢化形式具有较高的电子质量。推导运输和重组参数。 Ta-C:H是一种低迁移率固体,其mu tau乘积约为10〜(-12)cm〜2V〜(-1),重组时间tau _r约为10〜(-7)s。在低能量激发下,光电导率在很宽的温度范围内显示出与光强度的线性关系。讨论了光导率与自旋缺陷中心密度之间的关系。紫外线用于激发载流子进入扩展状态。竞争性重组中心可能涉及高激发能。

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