Biomimetic Synthesis of Water Soluble Conductive Polypyrrole and Poly (3,4 ethylenedioxythiophene)

机译：仿生合成水溶性导电聚吡咯和聚（3,4乙二氧基噻吩）

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A novel biomimetic method for the synthesis of a conducting molecular complex of polypyrrole and of Poly(3,4 ethylenedioxythiophene) (PEDOT) in the presence of a polyelectrolyte, such as polystyrene sulfonate (SPS) is presented. A poly(ethylene glycol) modified hematin (PEG-Hematin) was used to catalyze the polymerization of pyrrole and of 3,4 ethylenedioxythiophene in the presence of SPS to form a Polypyrrole/SPS and PEDOT/SPS complex. UV-vis, FTIR, electrical conductivity and TGA studies for all complexes indicate the presence of a thermally stable and electrically conductive form of these polymers. Furthermore the presence of SPS in this complex provides a unique combination of properties such as processability and water-solubility. Water-soluble polypyrrole opens new avenues for the fabrication of novel biosensors.

机译：提出了一种新型的仿生方法，用于在聚电解质（如聚苯乙烯磺酸盐（SPS））存在下合成聚吡咯和聚（3,4乙二氧基噻吩）（PEDOT）的导电分子配合物。在SPS的存在下，使用聚乙二醇修饰的血凝素（PEG-血红素）催化吡咯和3,4-乙撑二氧噻吩的聚合反应，从而形成聚吡咯/ SPS和PEDOT / SPS络合物。对所有配合物的紫外可见，FTIR，电导率和TGA研究表明，这些聚合物存在热稳定和导电形式。此外，这种复合物中SPS的存在提供了性能（例如可加工性和水溶性）的独特组合。水溶性聚吡咯为新型生物传感器的制造开辟了新途径。

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《Symposium on Electronics on Unconventional Substrates―Electrotextiles and Giant-Area Flexible Circuits Dec 2-3, 2002 Boston, Massachusetts, U.S.A.》|2002年|p.201-206|共6页
会议地点 Boston MA(US);Boston MA(US)
作者
Ferdinando F. Bruno; Jacqueline M. Fortier; Ramaswamy Nagarajan; Sucharita Roy; Jayant Kumar; Lynne A. Samuelson;
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Materials Science Team, Natick Soldier Center, U.S. Army Soldier and Biological, Chemical Command, Natick, MA 01760;

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正文语种 eng
中图分类一般工业技术;
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专利

1. Biomimetic synthesis of water soluble conductive polypyrrole and poly(3,4-ethylenedioxythiophene) [J] . Bruno FF., Nagarajan R., Roy S., Journal of Macromolecular Science. Pure and Applied Chemistry . 2003,第12期

机译：仿生合成水溶性导电聚吡咯和聚（3,4-乙撑二氧噻吩）
2. Electrochemical and chemical synthesis and characterization of sulfonated poly(3,4-ethylenedioxythiophene): A novel water-soluble and highly conductive conjugated oligomer [J] . Zotti G., Zecchin S., Schiavon G., Macromolecular chemistry and physics . 2002,第13期

机译：磺化聚（3,4-乙撑二氧噻吩）的电化学合成及表征：新型水溶性高导电共轭低聚物
3. Electrochemical synthesis and structural studies of polypyrroles, poly(3,4-ethylenedioxythiophene)s and copolymers of pyrrole and 3,4-ethylenedioxythiophene on carbon fibre microelectrodes [J] . Sarac AS., Sonmez G., Cebeci FC. Journal of Applied Electrochemistry . 2003,第3a4期

机译：碳纤维微电极上聚吡咯，聚（3,4-乙撑二氧噻吩）以及吡咯与3,4-乙撑二氧噻吩的共聚物的电化学合成和结构研究
4. Biomimetic Synthesis of Water Soluble Conductive Polypyrrole and Poly (3,4 ethylenedioxythiophene). [C] . Ferdinando F. Bruno, Jacqueline M. Fortier, Ramaswamy Nagarajan, Materials Research Society Symposium . 2003

机译：水溶性导电聚吡咯和聚（3,4乙二氧噻吩）的仿生合成。
5. Properties and Applications of Vapor Phase Polymerized Poly(3,4-Ethylenedioxythiophene) as Thin Film Electrode, Supercapacitor and Conductive Filler [D] . Li, Boxiao. 2020

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7. Facile synthesis of highly processable and water dispersible polypyrrole and poly(3,4-ethylenedioxythiophene) microspheres for enhanced supercapacitive performance [O] . Yu Liu, Anthony P.F. Turner, Maojun Zhao, 2018

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Biomimetic Synthesis of Water Soluble Conductive Polypyrrole and Poly (3,4 ethylenedioxythiophene)

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