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EFFECT OF PROCESS VARIABLES AND DOPANTS ON CHARACTERISTICS OF ELECTROCHEMICALLY- DEPOSITED PEDOT FILMS

机译:过程变量和掺杂剂对电化学沉积的Peedot膜特性的影响

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摘要

Poly(3,4-ethlyenedioxythiophene), PEDOT, has found wide use in applications such as electrostatic coatings, antistatic layers and electrode materials in electronic devices. Electrochemical deposition of PEDOT is a prominent means of obtaining thin, uniform films. However, the relationship of these films' properties to their morphological structure is still poorly understood. We have prepared PEDOT films by electrochemical oxidation of monomer (3,4-ethylenedioxythiophene), EDOT, under constant current conditions, employing a variety of electrolytes, and processing conditions. We report the effect of using different dopants, deposition time, deposition temperature and current density on the observed conductivity of PEDOT films. Atomic force microscopy studies were carried out to determine the possible effect of the process variables on the resulting film morphology. Also, the effect of residual solvent on the conductivity of the films was studied by thermogravimetric analysis (TGA).
机译:聚(3,4-乙二氧基二氧噻吩),PEDOT,已广泛用于电子设备中的静电涂料,抗静电层和电极材料等应用中。 PEDOT的电化学沉积是获得薄而均匀的薄膜的重要方法。但是,这些膜的性质与其形态结构之间的关系仍然知之甚少。我们通过在恒定电流条件下,采用多种电解质和加工条件,通过单体(3,4-乙撑二氧噻吩)EDOT的电化学氧化,制备了PEDOT膜。我们报告了使用不同的掺杂剂,沉积时间,沉积温度和电流密度对观察到的PEDOT膜电导率的影响。进行了原子力显微镜研究,以确定工艺变量对所得膜形态的可能影响。此外,还通过热重分析(TGA)研究了残留溶剂对薄膜电导率的影响。

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