【24h】

Growth kinetics of quantum size ZnO particles

机译:量子尺寸ZnO颗粒的生长动力学

获取原文
获取原文并翻译 | 示例

摘要

Colloidal chemistry techniques were used to synthesize ZnO particles in the nanometer size regime. The particle aging kinetics were determined by monitoring the optical band edge absorption and using the effective mass model to approximate the particle size as a function of time. We show that the growth kinetics of the ZnO particles follow the Lifshitz, Slyozov, Wagner theory for Ostwald ripening. In this model, the higher curvature and hence chemical potential of smaller particles provides a driving force for dissolution. The larger particles continue to grow by diffusion limited transport of species dissolved in solution.
机译:胶体化学技术用于合成纳米尺寸的ZnO颗粒。通过监测光学带边缘吸收并使用有效质量模型来近似随时间变化的粒度来确定颗粒老化动力学。我们表明,ZnO颗粒的生长动力学遵循Lostshitz,Slyozov,Wagner理论进行Ostwald熟化。在该模型中,较高的曲率以及较小颗粒的化学势提供了溶解的驱动力。较大的颗粒通过扩散限制溶解在溶液中的物质的运输而继续生长。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号