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Formulating Options for Aerosol Insecticides

机译:制定气雾剂的选择

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With ever tightening VOC regulations for consumer insecticides, formulators are being pushed to use more water and/or more LVP (low vapor pressure) fluids that are not reportable as VOCs in their products. The particular choice of LVP fluid and its concentration may also affect the biological performance of insecticide formulations. To demonstrate these effects, a variety of hydrocarbon LVP carrier fluids were combined with the insecticides S-bioallethrin~5 and deltamethrin~6 in both solvent and water-based insecticide formulations. Experiments were conducted to evaluate knockdown and residual activity against German cockroaches. Data indicated that use of hydrocarbon LVP carrier fluids with higher levels of normal paraffins resulted in faster knockdown of the cockroaches under a variety of test conditions. Higher concentrations of hydrocarbon LVP carrier fluids in water-based formulations also enhanced their knockdown performance. The residual activities of water-based formulations, inferred from the lengths of time the formulations remained efficacious after they were applied to ceramic tile and painted plywood, were adversely affected by higher concentrations of normal paraffins or LVP hydrocarbons. The results suggest that normal paraffins and higher concentrations of LVP hydrocarbon fluids may increase the penetration of the formulations into insect and household surfaces. With the insects this leads to faster intake of insecticide. With the household surfaces this reduces insecticide availability. One can use this information to select active ingredients, LVP fluids, and their concentrations, along with other formulants, to optimize formulation performance for specific application requirements and meet VOC regulations. Of the LVP hydrocarbon fluids tested, a mixed aliphatic fluid with a moderate concentration (20% w/w) of normal paraffins appeared to offer the best balance of properties for use in crawling insect killers.
机译:随着针对消费性杀虫剂的VOC法规日益严格,配方设计师被迫使用更多的水和/或更多的LVP(低蒸气压)液体,这些液体在其产品中均不可作为VOC报告。 LVP液的特殊选择及其浓度也可能会影响杀虫剂制剂的生物学性能。为了证明这些效果,在溶剂型和水基杀虫剂配方中,将多种烃类LVP载液与杀虫剂S-bioallethrin〜5和溴氰菊酯〜6混合使用。进行实验以评估对德国蟑螂的击倒和残余活性。数据表明,在各种测试条件下,使用含高含量正链烷烃的烃类LVP载液会导致蟑螂的快速击倒。水基制剂中较高浓度的烃类LVP载液也提高了其击倒性能。从配方在瓷砖和彩绘胶合板上使用后保持有效的时间长度推断,水性配方的残留活性受到正链烷烃或LVP烃浓度较高的不利影响。结果表明,正构烷烃和较高浓度的LVP烃液可能会增加制剂向昆虫和家庭表面的渗透。对于昆虫,这导致更快地摄入杀虫剂。在家用表面上,这降低了杀虫剂的利用率。可以使用此信息来选择活性成分,LVP流体及其浓度以及其他配方,以针对特定应用需求优化配方性能并满足VOC法规。在测试的LVP烃类流体中,具有中等浓度(20%w / w)正构链烷烃的混合脂肪族流体似乎可提供最佳的性能平衡,以用于爬行杀虫剂。

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