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Passivation of Defects in ZnO by Hydrogen Plasma Irradiation

机译:氢等离子体辐照钝化ZnO中的缺陷

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摘要

Hydrogen doping effects on luminescence properties of bulk ZnO samples were examined by using a pulse-modulated plasma irradiation technique. Three kinds of ZnO samples, including both single- and poly-crystals, were employed as specimens. Secondary-ion-mass-spectroscopy analysis revealed that the surface layer to 100 nm was doped with hydrogen after the irradiation and its concentration was in the order of 10~(17) cm~(-3). The efficiency of band edge emission was increased by the hydrogenation. However, the degree of the improvements depended on impurity and defect concentration in the original samples.
机译:通过使用脉冲调制等离子体辐射技术,研究了氢掺杂对块状ZnO样品的发光性能的影响。三种ZnO样品(包括单晶和多晶)均用作样品。二次离子质谱分析表明,辐照后至100 nm的表面层均掺杂有氢,其浓度约为10〜(17)cm〜(-3)。氢化增加了带边缘发射的效率。但是,改善的程度取决于原始样品中的杂质和缺陷浓度。

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