首页> 外文会议>Symposium on Quasicrystals held November 30-December 2,1998,Boston,Massachusetts,U.S.A. >Chemicla disorder and columnar vacancies in ideal decagonal Al-Ni-Co Quasicrystals
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Chemicla disorder and columnar vacancies in ideal decagonal Al-Ni-Co Quasicrystals

机译:理想十边形Al-Ni-Co准晶体中的化学无序和柱状空位

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Atomic-resolution Z-contrast images provide conclusive evidence for chemcial disorder in an ideal Al-Ni-Co quasicrystal.The so-called basic Ni-rich,high temeprature,quasiperiodic structure exhibits chemical disorder at the center of the 2 nm diameter clusters that involves both the Al and Ni(Co) atoms.the atomic structure of the 2 nm clusters is derived directly from the images and differs from previous models.The presence of closely-spaced,half-occupied atomic columns (or columnar vacancies) in specific rings within the clusters is directly observed.We propsoe that these columnar vacancies mediate the phason flips necessary for transformation to random tiling.
机译:原子分辨率的Z对比图像为理想的Al-Ni-Co准晶体中的化学无序提供了确凿的证据。所谓的富碱,高Temeprature,准周期的基本结构在2 nm直径簇的中心表现出化学无序,包含Al和Ni(Co)原子.2 nm团簇的原子结构直接从图像得出,与以前的模型不同。在特定情况下,存在紧密间隔的半占用原子柱(或柱状空位)直接观察到簇中的环。我们建议这些柱状空位介导转换为随机平铺所需的相移。

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