Electrochemical Investigations of Carbonyl Complexation by Lewis Acids

机译：路易斯酸对羰基络合的电化学研究

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The complexation of 9-fluorenone and benzophenone by hafnium salts in acetonitrile/0.2M TEA BF4 has been studied. From cyclic voltammetric studies, it has been found that both Hfi(TfO)_4 and HfCl_4 form a 1 : 1 complex with 9-fluorenone. Benzophenone also forms a 1 : 1 complex with Hf{TfO)_4. The electrochemical behavior of HfCl_4 in AN / 0.2M TEA BF_4 has also been investigated.

机译：研究了salts盐在乙腈/0.2M TEA BF4中对9-芴酮和二苯甲酮的络合作用。从循环伏安研究中，已经发现Hfi（TfO）_4和HfCl_4与9-芴酮形成1：1络合物。二苯甲酮还与Hf {TfO）_4形成1：1的复合物。还研究了HfCl_4在AN / 0.2M TEA BF_4中的电化学行为。

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《Synthetic and mechanistic organic electron transfer reactions》|2009年|p.117-121|共5页
会议地点 Vienna(AT);Vienna(AT)
作者
G. T. Cheek;
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作者单位

Department of Chemistry, U S Naval Academy, Annapolis, Maryland 21402, USA;

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原文格式 PDF
正文语种 eng
中图分类生物医学工程;
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1. Carbonyl Activation by Borane Lewis Acid Complexation: Transition States of H_2 Splitting at the Activated Carbonyl Carbon Atom in a Lewis Basic Solvent and the Proton-Transfer Dynamics of the Boroalkoxide Intermediate [J] . Mojgan Heshmat, Timofei Privalov Chemistry: A European journal . 2017,第38期

机译：硼烷路易斯酸络合的羰基活化：在Lewis碱性溶剂中活性羰基碳原子的H_2分裂的过渡状态和硼甲烷烃中间体的质子转移动力学
2. Defining the Conformation of Lewis Acid/Lewis Base Complexes: Crystallographic Evidence for Simultaneous a and n Donation by a Carbonyl Group to a Divalent Boron Lewis Acid [J] . Michael C. Amendola, Kenneth E. Stockman, Diego A. Hoic, Angewandte Chemie . 1997,第3期

机译：定义路易斯酸/路易斯碱配合物的构象：羰基同时向二价硼路易斯酸供a和n的晶体学证据
3. Testing the nature of reaction coordinate describing interaction of H-2 with carbonyl carbon, activated by Lewis acid complexation, and the Lewis basic solvent: A Born-Oppenheimer molecular dynamics study with explicit solvent [J] . Heshmat Mojgan, Privalov Timofei The Journal of Chemical Physics . 2017,第9期

机译：测试描述H-2与羰基碳相互作用的反应坐标的性质，由路易斯酸络合激活，Lewis碱性溶剂：具有明确溶剂的出生 - 对立海盗分子动力学研究
4. Electrochemical Investigations of Carbonyl Complexation by Lewis Acids [C] . G. T. Cheek Symposium on synthetic and mechanistic organic electron transfer reactions . 2010

机译：路易斯酸的羰基络合的电化学研究
5. Beyond alkyl transfer: Synthesis of main group metal (Mg, Ca, Zn) silyl and tris(oxazolinyl)borato complexes and their stoichiometric and catalytic reactions with borane Lewis acids and carbonyls. [D] . Lampland, Nicole Lynn. 2015

机译：超越烷基转移：合成主族金属（Mg，Ca，Zn）甲硅烷基和三（恶唑啉基）硼酸盐络合物，以及它们与硼烷路易斯酸和羰基化合物的化学计量和催化反应。
6. Nucleophilicities of Lewis Bases B and Electrophilicities of Lewis Acids A Determined from the Dissociation Energies of Complexes B⋯A Involving Hydrogen Bonds Tetrel Bonds Pnictogen Bonds Chalcogen Bonds and Halogen Bonds [O] . Ibon Alkorta, Anthony C. Legon 2017

机译：Lewis碱B的亲核性和Lewis酸A的亲电性由涉及氢键Tetrel键Pnictogen键硫属元素键和卤素键的配合物B⋯A的解离能确定
7. Beyond alkyl transfer: synthesis of main group metal (Mg, Ca, Zn) silyl and tris(oxazolinyl)borato complexes and their stoichiometric and catalytic reactions with borane Lewis acids and carbonyls [O] . Lampland, Nicole Lynn 2015

机译：超越烷基转移：主族金属（Mg，Ca，Zn）甲硅烷基和三（恶唑啉基）硼酸盐络合物的合成及其与硼烷路易斯酸和羰基化合物的化学计量和催化反应
8. Macrocycles Containing Tin. Through Space Cooperative Binding and High Size Selectivity in the Complexation of Chloride Ion by Lewis Acidic Macrobicyclic Hosts [R] . Newcomb, M., Horner, J. H., Blanda, M. T. 1987

机译：含有锡的大环。通过空间协同结合和路易斯酸性大环化合物主体在氯离子络合中的高尺寸选择性

Electrochemical Investigations of Carbonyl Complexation by Lewis Acids

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