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Validation of an empirical ozone model

机译:经验臭氧模型的验证

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摘要

The forecast of Ozone peaks has very important applications, such as control by authorities of the level of this pollutant, and it is also a necessary tool in Environmental Impact Assessment. Determinists and statistical models can estimate these levels, but they are very expensive to develop and apply, and it takes a long time to run the model. In this paper the authors suggest the use of an empirical model, proposed by Chang and Rudy, where it is related the ratio non-methane organic gasesitrogen oxides (NMOG/NO_x) with the tropospheric Ozone levels reached. The model has been validated with data from different stations over Catalonia (Spain). Finally, it can be concluded that the model is a reasonably effective tool to predict tropospheric Ozone peaks and the range of concentrations that are going to be reached, although the system tends to slightly overestimate the mean values of Ozone. The model works better in NMOG-rich regime than in low values of NMOG/NO_x ratio, so the fit of the model to real data is higher in non-urban stations than in those placed in populated area where emissions of NO_x are proportionally higher.
机译:臭氧峰值的预测具有非常重要的应用,例如由当局控制这种污染物的含量,它也是环境影响评估中的必要工具。确定论者和统计模型可以估计这些水平,但是它们的开发和应用非常昂贵,并且运行模型需要很长时间。在本文中,作者建议使用由Chang和Rudy提出的经验模型,该模型将非甲烷有机气体/氮氧化物(NMOG / NO_x)的比率与对流层臭氧水平达到相关。该模型已使用来自加泰罗尼亚(西班牙)不同站点的数据进行了验证。最后,可以得出结论,该模型是预测对流层臭氧峰值和将要达到的浓度范围的合理有效工具,尽管该系统倾向于略微高估臭氧的平均值。该模型在NMOG丰富的区域比在NMOG / NO_x比率低的情况下效果更好,因此该模型对真实数据的拟合在非城市站点中要比在人口密集地区的NO_x排放成比例地更高。

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