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Study of MgO-Based Desulfurizer in Hot Metal Desulfurization

机译:铁水脱硫中MgO基脱硫剂的研究

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摘要

This paper has investigated a new desulfurizer for iron and steel industry to make up the lackness of magnesium-based desulfurizer. In order to explore the desulfurization process of hot metal by the new desulfurizer, both the thermodynamics and experiments have been studied.. The results of thermodynamics indicated that, under the standard condition, the lowest reaction temperatures of MgO + C and MgO +Si were 1846℃ and 2132℃ and the pressure of Mg vapor at the hot metal temperature were 0.2-0.5kPa and 0.0050.01kPa, respectively. In the case of reaction between MgO and Al, the calculated starting reaction temperature under standard condition was 1475℃, and the pressure of Mg vapor was distributed from 27 kPa to 45kPa at the hot metal temperature, showing that it was easy to happen the reaction of MgO+Al. The experimental results displayed that the desulfurization efficiency was only 42.31% by the desulfurizer of MgO and C, while the effect of MgO+ Al and MgO+ Al-Si was good, since the desulfurization efficiencies were above 85%, and the lowest sulfur content was below 40×10-6.
机译:本文研究了一种新型的钢铁工业脱硫剂,以弥补镁基脱硫剂的不足。为了探索新型脱硫剂对铁水的脱硫过程,进行了热力学和实验研究,热力学结果表明,在标准条件下,MgO + C和MgO + Si的最低反应温度为1846℃和2132℃以及Mg蒸气在铁水温度下的压力分别为0.2-0.5kPa和0.0050.01kPa。在MgO和Al之间进行反应的情况下,计算出的标准条件下的起始反应温度为1475℃,并且Mg蒸气的压力在铁水温度下从27 kPa分布到45kPa,这表明该反应很容易发生MgO + Al。实验结果表明,MgO和C脱硫剂的脱硫效率仅为42.31%,而MgO + Al和MgO + Al-Si的脱硫效率均在85%以上,而最低硫含量在70%以下,效果很好。 40×10-6。

著录项

  • 来源
  • 会议地点 Shenyang(CN)
  • 作者单位

    School of Material and Metallurgy, Northeastern University, Shenyang 110004, Liaoning, China;

    School of Material and Metallurgy, Northeastern University, Shenyang 110004, Liaoning, China;

    School of Material and Metallurgy, Northeastern University, Shenyang 110004, Liaoning, China;

    School of Material and Metallurgy, Northeastern University, Shenyang 110004, Liaoning, China;

    School of Material and Metallurgy, Northeastern University, Shenyang 110004, Liaoning, China;

    School of Material and Metallurgy, Northeastern University, Shenyang 110004, Liaoning, China;

  • 会议组织
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 炼钢;
  • 关键词

    desulfurization; thermodynamics; MgO; Al; C; Al-Si;

    机译:脱硫热力学氧化镁;铝C;铝硅;

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