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Thermodynamic Modeling of Deoxidation Products and Inclusion Chemistry in Mn/Si Killed Tire-Cord Steel

机译:Mn / Si镇静轮胎钢丝中脱氧产物和夹杂物化学的热力学模型

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The present work deals with thermodynamic modeling of oxide systems, in the context of slags and inclusions in steelmaking. The work has emphasis on oxides encountered during the production of tire - cord steel. Control of inclusion chemistry and variation in eutectic temperature and eutectic composition of MnO-AljCVSiC^ slag system have been studied, using Thermo-CalcR software. Relatively low liquidus temperatures are obtained for ratio of MnO / SiO2 = 0.5 - 1.5 and AI2O3 content from 10-20 mass%. It has been observed that the addition of Alumina leads to further increase in the liquidus temperature. The stability of inclusions is analyzed in terms of free energy values of related slag systems; and an appropriate minimum of Gibbs free energy value of slag phase observed at around 50 ppm of Oxygen. The observations could not be verified using thermodynamic experiments, but have been compared with findings in the open literature.
机译:本工作涉及炼钢中的炉渣和夹杂物的情况下氧化物体系的热力学建模。这项工作着重于轮胎帘线钢生产过程中遇到的氧化物。使用Thermo-CalcR软件研究了MnO-AljCVSiC2渣系统的夹杂物化学控制以及共晶温度和共晶组成的变化。对于MnO / SiO 2的比= 0.5-1.5和Al 2 O 3含量为10-20质量%,可获得相对较低的液相线温度。已经观察到氧化铝的加入导致液相线温度的进一步升高。根据相关炉渣系统的自由能值分析夹杂物的稳定性;在氧气含量约为50 ppm时观察到的炉渣相的吉布斯自由能值的最小值。这些观察结果不能通过热力学实验来验证,但是已经与公开文献中的发现进行了比较。

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