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Siloxane Enhanced Elastomers

机译:硅氧烷增强的弹性体

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In a growing number of applications, thermoplastic elastomers (TPEs) are used as alternatives to thermoset rubber because of their ability to reduce the total fabrication cost and increase the design flexibility (as an example, the combination of soft and hard materials by overmolding). Like traditional thermoset rubbers, TPEs possess elastomeric properties. However, TPEs can be processed by conventional thermoplastic techniques such as injection molding, extrusion, and blow molding. Thermoplastic vulcanizates (TPVs) are an alloy type of TPE consisting of fully crosslinked rubber domains suspended in a continuous thermoplastic phase. The most commonly available TPV is based on the combination of polypropylene (PP) and EPDM rubber. As compared to thermoplastics, these materials offer some unique properties, such as lower compression set and greater resilience.Silicone based TPVs under the trade name of TPSiV~(TM) are a patented technology of Multibase, A Dow Corning Company. As an alloy type TPE, it combines the many unique properties of silicone rubber, such as excellent property retention at low and high temperatures as well as selected thermoplastics matrices. Previously the unique properties and applications of silicone TPVs utilizing nylon and thermoplastic urethane matrices have been presented (1). This paper will describe the properties and applications for silicone based TPVs utilizing polyolefm matrices.
机译:在越来越多的应用中,热塑性弹性体(TPE)可以替代热固性橡胶,因为它们能够降低总制造成本并提高设计灵活性(例如,通过包覆成型将软硬材料结合在一起)。像传统的热固性橡胶一样,TPE具有弹性。但是,可以通过常规热塑性技术(例如注塑,挤出和吹塑)加工TPE。热塑性硫化橡胶(TPV)是TPE的合金类型,由悬浮在连续热塑性相中的完全交联的橡胶区域组成。最常用的TPV基于聚丙烯(PP)和EPDM橡胶的组合。与热塑性塑料相比,这些材料具有一些独特的性能,例如更低的压缩永久变形和更大的回弹力。商标为TPSiV〜(TM)的硅基TPV是道康宁公司Multibase的专利技术。作为合金型TPE,它结合了硅橡胶的许多独特性能,例如在低温和高温下具有出色的性能保持性,以及精选的热塑性塑料基体。以前,已经提出了利用尼龙和热塑性聚氨酯基质的有机硅TPV的独特性能和应用(1)。本文将介绍利用聚烯烃基质的有机硅基TPV的性能和应用。

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