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LASER SURFACE TREATMENT OF A BIODEGRADABLE POLYMER AT VARYING FLUENCES

机译:可变通量的可生物降解聚合物的激光表面处理

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For biodegradable polymers such as poly (L-lactic acid) (PLLA), material crystallinity has a considerable effect on degradation and physical properties. In this work, the effects of laser fluence of a 355 nm UV Q-switched Nd-YAG laser on the crystallinity and conformation at the surface of PLLA films and the factors affecting the transformation are investigated. Electron microscopy, X-ray diffraction, and infrared spectroscopy are used to study the effects at varying fluences. The melting and crystallization kinetics of PLLA are examined to understand the important parameters that determine the overall crystallinity. Potentially, laser surface treatment at varying fluences can be used to spatially control the generation of a polymer surface with an altered degree of crystallinity. Such a structure may have applications including time-released drug delivery.
机译:对于可生物降解的聚合物,例如聚(L-乳酸)(PLLA),材料的结晶度对降解和物理性能有很大影响。在这项工作中,研究了355 nm UV Q开关Nd-YAG激光的能量密度对PLLA膜表面的结晶度和构象的影响以及影响转变的因素。电子显微镜,X射线衍射和红外光谱用于研究不同注量下的影响。检查了PLLA的熔融和结晶动力学,以了解决定总体结晶度的重要参数。潜在地,可以使用具有不同注量的激光表面处理来在空间上控制具有改变的结晶度的聚合物表面的产生。这样的结构可以具有包括延时释放的药物递送的应用。

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