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Enhanced Ion Transport in 2-nm Silica Nanochannels

机译:2 nm二氧化硅纳米通道中增强的离子传输

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Fluidic nanochannels with 1-2 nm in size are functional mimics of protein channels, and have recently attracted significant attention for exploring the transport of ions and molecules in confined liquids. Here we report ion transport in 2 nm deep nanochannels fabricated by standard semiconductor manufacturing processes. Ion transport in these nanochannels is dominated by surface charge until the ion concentration exceeds 100 mM. At low concentrations, proton mobility increases by a factor of four over its bulk value, possibly due to overlap of the two hydration layers adjacent to hydrophilic surfaces. The mobility of K+/Na + ions also increases as the bulk concentration decreases, although the reasons are not completely understood.
机译:1-2 nm大小的流体纳米通道是蛋白质通道的功能模拟物,最近在探索密闭液体中离子和分子的运输方面引起了极大的关注。在这里,我们报告了通过标准半导体制造工艺制造的2 nm深纳米通道中的离子传输。这些纳米通道中的离子传输受表面电荷支配,直到离子浓度超过100 mM。在低浓度下,质子迁移率在其总体值上增加了四倍,这可能是由于与亲水表面相邻的两个水合层重叠造成的。 K + / Na +离子的迁移率也随着体积浓度的降低而增加,尽管其原因尚不完全清楚。

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