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Magnetic and Magneto-Optical Properties of Composite Films of Ferromagnetic Ultrafine Particles Dispersed in Polymethyl Methacrylate

机译:分散在聚甲基丙烯酸甲酯中的铁磁超细颗粒复合膜的磁和磁光性能

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Magnetic and magneto-optical properties of composite films of ultrafine fcc cobalt particles dispersed in a transparent PMMA plastic matrix have been investigated. The colloidal solutions suspended by cobalt particles were synthesized by decomposing dicobalt octacarbonyl dissolved in toluene together with PMMA. The average particle diameter, ranging 3.8nm to 15.9nm, was controlled by the solvent concentration. Films were formed by spin-coating the solutions on glass plates and were dried by evacuating toluene. The Faraday rotation θ_F of the films had a unique wavelength dependence as well as the optical absorption. θ_F had a maximum around 390nm of light wavelength irrespective of the particles size d, but the spectrum shape varied with d. The most sharpened spectrum was observed around d=9nm, when the optical absorption was the largest.
机译:研究了分散在透明PMMA塑料基质中的超细fcc钴颗粒复合膜的磁和磁光性能。通过分解溶于甲苯的八羰基二钴和PMMA合成了钴颗粒悬浮的胶体溶液。通过溶剂浓度控制3.8nm至15.9nm的平均粒径。通过将溶液旋涂在玻璃板上形成薄膜,并通过排空甲苯进行干燥。膜的法拉第旋转θ_F具有独特的波长依赖性以及光吸收。 θ_F的最大波长约为390nm,与粒径d无关,但光谱形状随d的变化而变化。当光吸收最大时,在d = 9nm附近观察到最锐化的光谱。

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