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Supramolecular species immobilized in oxide xerogels as optical materials

机译:固定在氧化物干凝胶中的超分子物质作为光学材料

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Abstract: Supramolecular photochemistry is an emerging and rapidly growing research area, most attractive from fundamental point of view and very promising for a variety of applications. An appropriate assembly of molecular components capable of performing light-induced functions can be called a photochemical molecular device (PMD). The most functions that can be performed by PMDs are (i) generation and migration of electronic energy, (ii) photoinduced vectorial transport of electric charge, (iii) photoinduced conformational changes, and (iv) control and tuning of photochemical and photophysical properties. On the other hand, by the low-temperature sol-gel process are produced rigid and porous xerogel materials. The important point is that the sol-gel materials are transparent, therefore can be used as hosts for supramolecular photo-chemical devices. !35
机译:摘要:超分子光化学是一个新兴的且正在快速发展的研究领域,从基本的角度来看最有吸引力,并且在各种应用中非常有前途。能够执行光诱导功能的分子组分的适当组装可以称为光化学分子装置(PMD)。 PMD可以执行的大多数功能是(i)电能的产生和迁移,(ii)光诱导的电荷矢量传输,(iii)光诱导的构象变化以及(iv)控制和调节光化学和光物理性质。另一方面,通过低温溶胶-凝胶法生产刚性和多孔的干凝胶材料。重要的是溶胶-凝胶材料是透明的,因此可以用作超分子光化学装置的主体。 !35

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