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Design, syntheses and characterization of copper(II) inorganic-organic hybrid coordination polymers based on beta-cyanodiketonates and telechelic nitrogenous spacers.

机译：基于β-氰基二酮酸酯和远螯氮间隔基的铜（II）无机-有机杂化配位聚合物的设计，合成和表征。

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The design and preparation of coordination networks assembled via discrete inorganic and organic molecular components has undergone rapid expansion in the field of supramolecular chemistry over the past decade. Interest in this area is driven by fascinating structural diversity and potential applicability of metal-based molecular architectures as functional materials. Although numerous efforts have been geared toward controlling network formation through judicious choice of metal ions, spacer ligands and reaction conditions, the design of self-assembled networks based on multifunctional metal beta-diketonate templates remains a relatively unexplored avenue in coordination chemistry. This dissertation focuses on the design, syntheses and characterization of multifunctional beta-cyanodiketones and their utility for constructing one- and two-dimensional inorganic-organic hybrid materials from prefabricated Cu(II) beta-cyanodiketonate constituents.

机译：在过去的十年中，通过离散的无机和有机分子组分组装的配位网络的设计和制备在超分子化学领域迅速发展。令人着迷的结构多样性和基于金属的分子结构作为功能材料的潜在适用性推动了对该领域的兴趣。尽管已经做出了许多努力来通过明智地选择金属离子，间隔基配体和反应条件来控制网络形成，但是基于多功能金属β-二酮酸酯模板的自组装网络的设计在配位化学中仍然是一个相对未开发的途径。本论文的重点是多功能β-氰基二酮的设计，合成和表征，以及它们在预制的β-氰基二酮铜（II）构成一维和二维无机-有机杂化材料中的应用。

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作者
Silvernail, Carter Martin.;
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作者单位

The University of Nebraska - Lincoln.;

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授予单位 The University of Nebraska - Lincoln.;
学科 Chemistry Inorganic.
学位 Ph.D.
年度 2005
页码 131 p.
总页数 131
原文格式 PDF
正文语种 eng
中图分类无机化学;
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Design, syntheses and characterization of copper(II) inorganic-organic hybrid coordination polymers based on beta-cyanodiketonates and telechelic nitrogenous spacers.

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