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Theoretical and spectroscopic studies of molecular systems for charge transfer and energy storage and transfer.

机译：用于电荷转移以及能量存储和转移的分子系统的理论和光谱学研究。

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摘要

Efficient charge transfer and energy storage and transfer have become increasingly important in many areas of research and development. This is especially true for the development of optoelectronic devices, molecular electronics, and solar voltaic cells. Characterization of the photophysical properties of new molecular systems for these applications has emerged as an important field of research. Many molecular building blocks have been developed and understanding the properties of these systems at a fundamental level is essential for their successful implementation. This dissertation focuses on experimental and theoretical studies of some of these newly-developed molecular systems. Oxygen substituted dihydrobenzvalene is studied theoretically for potential use in energy storage applications. Spectroscopic studies center around the study of newly-developed molecules based on perylene and thiophene derivatives for device applications including nonlinear optics, photovoltaic cells, and molecular electronics. The importance of the synergy between theory and experiment is also demonstrated in the area of chemical education.
机译：在许多研究和开发领域，有效的电荷转移以及能量存储和转移已变得越来越重要。对于光电子器件，分子电子学和太阳能电池的开发尤其如此。用于这些应用的新分子系统的光物理性质的表征已经成为重要的研究领域。已经开发了许多分子构件，并且从根本上了解这些系统的性质对于其成功实施至关重要。本文主要研究这些新兴分子系统的实验和理论研究。理论上研究了氧取代的二氢苯并戊烯在能量存储应用中的潜在用途。光谱学研究围绕新开发的基于per和噻吩衍生物的分子的研究，这些器件用于非线性光学，光伏电池和分子电子学等设备。在化学教育领域也证明了理论与实验之间协同作用的重要性。

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  • 作者

    Scardino, Debra Jo.;

  • 作者单位

    The University of Mississippi.;

  • 授予单位 The University of Mississippi.;
  • 学科 Chemistry Physical.
  • 学位 Ph.D.
  • 年度 2012
  • 页码 137 p.
  • 总页数 137
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

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