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The agglomeration of nickel laterite ore.

机译:红土镍矿的团聚。

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摘要

Nickel laterites are becoming more attractive for nickel production due to the depletion of high grade nickel sulfide ores. Since the nickel content in laterites is relatively low, processes to recover nickel from these resources must be economical and robust. Heap leaching has been commonly used to treat low grade copper and gold ores due to its low capital and operating costs. Therefore, research and development in nickel heap leaching technology is compelling. However, nickel laterites typically contain significant quantities of fine particles and clay minerals which could contribute to heap leaching difficulties.;Agglomeration has been used to improve heap performance in copper and gold heap leaching. Experiments have been conducted to evaluate the performance of agglomeration in nickel heap leaching. In this study, nickel laterite ores were agglomerated with various conditions, including moisture content, acid concentration, retention time and drum rotation speed. Size distribution, permeability and electrical conductivity data of agglomerates were collected to study the effects of agglomeration conditions on agglomerate qualities. The agglomerates were then leached with diluted sulfuric acid for 90 days. Nickel and other interested element extraction rates were obtained by ICP-OES. Mineralogy of feeds, agglomerates and leached residuals were also investigated.;From the experimental data, we found that agglomerate size distributions (ASD) correlated with the agglomeration volume of solution added agglomeration. The drum rotation speeds did not a have significant effect on agglomerate size distribution. Increasing mixing times during agglomeration led to increases in agglomerate sizes. Hydraulic conductivity (permeability) of the agglomerate bed is related to the agglomerate size distribution. The electrical conductivity of nickel laterite agglomerate beds depends on the sulfuric acid concentration used during agglomeration, solution addition, external compression and nature of the ores. Nonetheless, the values depend heavily on the sulfuric acid concentration.;The highest extraction rate of nickel, cobalt, iron, aluminum, magnesium and manganese in these experiments are 58%, 38%, 22%, 28%, 48% and 27%, respectively. The feed contains mainly silico-ferruginous plasma, goethite and clay minerals along with other minor phases. In agglomerates, a new sulfate phase was observed. The main element in this phase is sulfur. The "sulfate" phase and clays appear to dissolve during leaching. The nickel that remained unleached predominantly resides in the silico-ferruginous plasma.
机译:由于高级硫化镍矿石的枯竭,镍红土矿对镍生产的吸引力越来越大。由于红土中的镍含量较低,因此从这些资源中回收镍的过程必须经济且稳健。堆浸由于其较低的资本和运营成本而已被普遍用于处理低品位的铜和金矿石。因此,镍堆浸技术的研究和开发是引人注目的。但是,镍红土通常含有大量细颗粒和粘土矿物,这可能会增加堆浸的难度。结块已被用来改善铜和金堆浸的堆性能。已经进行了实验以评估镍堆浸中的附聚性能。在这项研究中,红土镍矿在各种条件下团聚,包括水分含量,酸浓度,保留时间和转鼓转速。收集附聚物的粒度分布,渗透性和电导率数据,以研究附聚物条件对附聚物质量的影响。然后将附聚物用稀硫酸浸提90天。通过ICP-OES获得镍和其他感兴趣的元素提取率。还研究了饲料的矿物学,团聚体和浸出残渣。根据实验数据,我们发现团聚体的粒度分布(ASD)与溶液附聚的团聚体积相关。鼓转速对附聚物尺寸分布没有显着影响。附聚过程中混合时间的增加导致附聚物尺寸的增加。附聚物床的水力传导率(渗透率)与附聚物的粒度分布有关。红土镍矿附聚床的电导率取决于附聚过程中使用的硫酸浓度,溶液添加,外部压缩和矿石性质。但是,该值在很大程度上取决于硫酸浓度。在这些实验中,镍,钴,铁,铝,镁和锰的最高提取率分别为58%,38%,22%,28%,48%和27% , 分别。进料主要包含硅铁质血浆,针铁矿和粘土矿物以及其他次要相。在附聚物中,观察到新的硫酸盐相。此阶段的主要元素是硫。在浸出过程中,“硫酸盐”相和粘土似乎溶解了。保留未浸出的镍主要存在于硅铁质等离子体中。

著录项

  • 作者

    Janwong, Adirek.;

  • 作者单位

    The University of Utah.;

  • 授予单位 The University of Utah.;
  • 学科 Engineering Mining.
  • 学位 Ph.D.
  • 年度 2012
  • 页码 201 p.
  • 总页数 201
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

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