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Autothermal catalytic reforming with integrated internal heat exchange and enhanced oxygen feed: Design and construction of a device to convert gasoline into hydrogen for use in fuel cell automobiles.

机译:具有集成的内部热交换和增强的供氧功能的自热催化重整:设计和制造一种将汽油转化为氢气的设备,用于燃料电池汽车。

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A design is presented for an autothermal catalytic reformer for gasoline that incorporates integral internal heat exchange and oxygen enrichment of the feed gas to improve performance. Internal integral heat exchange is intended to transfer heat from the exothermic partial oxidation zone of the reformer to the endothermic steam reforming zone without the use of dedicated heat exchange equipment. Oxygen enrichment of air up to 70% by volume is shown to increase the total hydrogen concentration in the product gas by over 70% relative to using normal air in the feed. Oxygen enhancement also reduces the O2:fuel ratio required to achieve thermoneutrality during a steady-state reaction by approximately 10% on a per mole of fuel basis. The reformer was built to provide approximately 7 kW equivalent of hydrogen. The main determinant of reformer proportions was catalyst pellet size. A system to test the performance of the reformer was also designed. This system was capable of precisely metering iso-octane, water, and oxygen-enriched air to the reformer. The temperature profile in the reformer could be monitored by an array of thermocouples. Product gas flow rate was monitored by a mass flowmeter and product gas composition was determined using a gas chromatograph. The data collected can be used to measure the conversion of iso-octane to hydrogen in the autothermal reformer for a given feed rate of iso-octane, which is a measure of reactor performance.
机译:提出了一种针对汽油的自热催化重整器的设计,该设计结合了整体内部热交换和进料气的氧气富集功能,以提高性能。内部整体热交换旨在将热量从重整器的放热部分氧化区转移到吸热蒸汽重整区,而无需使用专用的热交换设备。与进料中使用普通空气相比,空气中富氧量高达70%的气体可将产品气中的总氢浓度提高70%以上。氧气的增加还会使在稳态反应期间达到热中性所需的O2:燃料比率按每摩尔燃料计降低约10%。该重整炉可提供约7 kW的氢当量。重整器比例的主要决定因素是催化剂颗粒尺寸。还设计了测试重整器性能的系统。该系统能够精确地计量重整炉中的异辛烷,水和富氧空气。重整器中的温度曲线可以通过热电偶阵列进行监控。用质量流量计监测产物气体的流速,并用气相色谱仪测定产物气体的组成。对于给定的异辛烷进料速率,收集的数据可用于测量自热重整器中异辛烷到氢气的转化率,这是反应器性能的度量。

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