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Blast furnace burden softening and melting phenomena.

机译:高炉炉料软化和熔化现象。

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摘要

The cohesive zone in the blast furnace, where ferrous burden materials soften and melt, greatly affects its performance. Minimizing the size and lowering the position of the cohesive zone will improve productivity and decrease the coke rate. This work was designed to better understand the softening and melting phenomena of ferrous feed materials. Different experimental techniques were used to allow the observation of different stages of softening and melting. Three pellets were used: Acid, Basic Fluxed (with dolomite) and Olivine Fluxed pellets.; The experiments performed in the Confocal Scanning Laser Microscope (CSLM) were designed to measure the temperature where liquid was first formed, as well as the evolution of its fraction. Also, by interrupting these experiments at different temperatures, it was possible to observe the changes in the microstructure with temperature. By using two different heating rates, it was possible to observe the effect of the residence time in the dissolution of particles in the early stages of melting. The three types of pellets used in this series of experiments were pre-reduced to wustite.; To observe the interaction between the pellets at high temperatures under load, experiments were performed in a resistance furnace with X-ray imaging equipment. The pellets were pre-reduced to 60% or 80% reduction degree (oxide basis), placed in a graphite crucible and heated under N2 gas flow. Besides the pictures, the displacement and temperature were also recorded. In this series, experiments were performed with individual pellets as well as with a mixed burden of Fluxed with Acid pellets at a ratio of 2:1.; The analysis of the interaction at the macrostructural and microstructural level was possible with samples obtained in experiments performed under load in an inductively heated furnace, which were interrupted at a specific point.; A computer slag model was used to estimate the effect of different elements on the melt onset at the slag-wustite interface. For this, CaO-SiO2-FeO isothermal sections at different temperatures, with and without the addition of MgO, Al2O3 and Na2O, at different content and permutations, were calculated. This model was also used to calculate pseudo-binary sections of FeO with different flux materials or gangue particles, with and without Na2O, in order to estimate the melting or dissolution behavior of these particles. Finally, this model was used to calculate the evolution of the liquid mass fraction with temperature. (Abstract shortened by UMI.)
机译:高炉中的粘结区(铁质物料软化和熔化)会极大地影响其性能。最小化尺寸并降低粘结区的位置将提高生产率并降低焦炭率。这项工作旨在更好地了解含铁原料的软化和熔化现象。使用了不同的实验技术来观察软化和熔化的不同阶段。使用了三种颗粒:酸,碱性助焊剂(含白云石)和橄榄石助焊剂。共聚焦扫描激光显微镜(CSLM)中进行的实验旨在测量液体首次形成时的温度及其馏分的演变。同样,通过在不同温度下中断这些实验,有可能观察到微观结构随温度的变化。通过使用两种不同的加热速率,有可能观察到停留时间对熔化早期颗粒溶解的影响。在这一系列实验中使用的三种类型的药丸被预先还原成钙铁矿。为了观察高温下在负荷下粒料之间的相互作用,在具有X射线成像设备的电阻炉中进行了实验。将粒料预先还原至还原度为60%或80%(以氧化物计),放入石墨坩埚中,并在N 2 气流下加热。除了图片,还记录了位移和温度。在该系列中,对单个颗粒以及以2:1的比例混合有酸颗粒的助焊剂进行了实验。使用在感应加热炉中负载下进行的实验中获得的样品,可以在宏观结构和微观结构水平上分析相互作用,这些样品在特定点处中断。使用计算机熔渣模型来估计不同元素对熔渣与铁水灰石界面处熔体开始的影响。为此,在有和没有添加MgO,Al 2 O 3 和Na的情况下,CaO-SiO 2 -FeO等温截面在不同温度下计算了不同内容和排列的 2 O。该模型还用于计算具有和不具有Na 2 的不同助熔剂材料或脉石颗粒的FeO的伪二元截面,以估计这些颗粒的熔融或溶解行为。最后,该模型用于计算液体质量分数随温度的变化。 (摘要由UMI缩短。)

著录项

  • 作者

    Nogueira, Paulo Freitas.;

  • 作者单位

    Carnegie Mellon University.;

  • 授予单位 Carnegie Mellon University.;
  • 学科 Engineering Metallurgy.
  • 学位 Ph.D.
  • 年度 2003
  • 页码 230 p.
  • 总页数 230
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 冶金工业;
  • 关键词

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