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Effect of co-doping on photosensitivity of teos sol-gel glasses.

机译:共掺杂对teos溶胶凝胶玻璃光敏性的影响。

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摘要

The creation of photosensitive centers in germano-silica sol-gel glasses related to oxygen deficient centers has been analyzed. The principal objectives are fabrication and studies of properties of germanium oxygen deficient centers (GODCs) and new centers in glass system. Dopants as aluminum and lithium ions were introduced in the glass. Formation and transformation of oxygen deficient centers are studied through the variation of optical absorption spectra of these specimens. Effect of UV irradiation on the samples was analyzed. Presence of small concentrations of lithium ions in germano-silica glasses promotes the formation of GODCs and enhances the photosensitive response of them improving the photochemical conversion of GODC to other centers. A new center [GeO4-/Li+] is formed. Summarizing, the doping of glass with aluminum and lithium ions enhances its photosensitivity, thus opening a new avenue in application of developed technique in fabrication of photosensitive devices for telecommunication industry.
机译:分析了与氧缺乏中心有关的锗硅溶胶凝胶玻璃中光敏中心的产生。主要目标是制造和研究锗氧缺乏中心(GODC)和玻璃系统新中心的性能。玻璃中引入了铝和锂离子等掺杂剂。通过改变这些样品的光吸收光谱,研究缺氧中心的形成和转变。分析了紫外线照射对样品的影响。锗硅玻璃中低浓度锂离子的存在促进了GODC的形成并增强了它们的光敏响应,从而改善了GODC向其他中心的光化学转化。形成一个新的中心[GeO4- / Li +]。综上所述,用铝和锂离子对玻璃进行掺杂增强了其光敏性,从而为开发用于电信行业的光敏器件的技术的应用开辟了一条新途径。

著录项

  • 作者单位

    University of Puerto Rico, Mayaguez (Puerto Rico).;

  • 授予单位 University of Puerto Rico, Mayaguez (Puerto Rico).;
  • 学科 Physics Optics.; Physics Condensed Matter.; Engineering Materials Science.
  • 学位 M.S.
  • 年度 2001
  • 页码 81 p.
  • 总页数 81
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 光学;工程材料学;
  • 关键词

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