首页> 外文学位 >Substitution chemistry of the cobalt complexes R carbon cobalt(3) nonacarbonyl (R = hydrogen, formyl radical) with the diphosphine ligand 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): Syntheses, x-ray structures, and reactivity.

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Substitution chemistry of the cobalt complexes R carbon cobalt(3) nonacarbonyl (R = hydrogen, formyl radical) with the diphosphine ligand 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): Syntheses, x-ray structures, and reactivity.

机译：用二膦配体4,5-双（二苯基膦基）-4-环戊烯-1,3-二酮（bpcd）取代钴络合物R的碳（9）碳羰基钴（R =氢，甲酰基）：合成，x射线结构和反应性。

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作者
Liu, Jie.;
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作者单位

University of North Texas.;

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授予单位 University of North Texas.;
学科 Inorganic chemistry.
学位 M.S.
年度 2001
页码 62 p.
总页数 62
原文格式 PDF
正文语种 eng
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1. Diverse ligand substitution behavior in the reaction of H_4O_s_4(CO)_(12) with 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd) and Me_3NO: Spectroscopic characterization of the diphosphine chelating and bridging isomers H_4O_s_4(CO)_(10)(bpcd) and the X-ray diffraction structures of the tetraosmium clusters H_4O_s_4(CO)_(11)(NMe_3) and 1,2-H_4O_s_4(CO)_(10)(NMe_3)(η~1-bpcd) [J] . William H. Watson, Srikanth Kandala, Michael G. Richmond Journal of Chemical Crystallography . 2006,第10期

机译：H_4O_s_4（CO）_（12）与4,5-双（二苯基膦基）-4-环戊烯-1,3-二酮（bpcd）和Me_3NO反应的不同配体取代行为：二膦螯合和桥联异构体的光谱表征H_4O_s_4（CO）_（10）（bpcd）和四os簇H_4O_s_4（CO）_（11）（NMe_3）和1,2-H_4O_s_4（CO）_（10）（NMe_3）（的X射线衍射结构） η〜1-bpcd）
2. Ligand substitution in HC(O)CCo3(CO)(9) with 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): Diphosphine ligand fluxionality, decarbonylation of the formyl moiety and competitive P-Ph bond cleavage reactivity [J] . Watson WH, Bodige SG, Ejsmont K, Journal of Organometallic Chemistry . 2006,第17期

机译：在HC（O）CCo3（CO）（9）中用4,5-双（二苯基膦基）-4-环戊烯-1,3-二酮（bpcd）进行配体取代：二膦配体通量，甲酰基部分的脱羰基和竞争性P- Ph键裂解反应
3. Acetylide participation in ligand substitution and P-C bond cleavage in the reaction between HRu3(CO)(9)(mu(3),eta(2),eta(2),eta(1)-C CPH) and 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd). Syntheses and X-ray structures of HRu3(CO)(7)[m [J] . Bott SG., Shen HF., Senter RA., Organometallics . 2003,第9期

机译：乙醛参与配体取代和PC键裂解HRu3（CO）（9）（mu（3），eta（2），eta（2），eta（1）-C CPH）和4,5-bis之间的反应（二苯基膦基）-4-环戊烯-1,3-二酮（bpcd）。 HRu3（CO）（7）[m]的合成及X射线结构
4. Substitution chemistry of ruthenium clusters with the diphosphine ligands: 4,5-bis(diphenylphosphino)-4-cyclo-penten-1,3-dione (BPCD), (Z)-Ph(2)PCH=CHPPh(2) and 3,4-bis(diphenylphosphino)-5-methoxy-2(5H)-furanone (BMF). [D] . Shen, Huanfeng. 1997

机译：具有二膦配体的钌簇的取代化学：4,5-双（二苯基膦基）-4-环戊烯-1,3-二酮（BPCD），（Z）-Ph（2）PCH = CHPPh（2）和3 ，4-双（二苯基膦基）-5-甲氧基-2（5H）-呋喃酮（BMF）。
5. Catalytic Hydrogenation Activity and Electronic Structure Determination of Bis(arylimidazol-2-ylidene)pyridine Cobalt Alkyl and Hydride Complexes [O] . Renyuan Pony Yu, Jonathan M. Darmon, Carsten Milsmann, -1

机译：双（芳基咪唑-2-亚甲基）吡啶钴钴和氢化物配合物的催化加氢活性和电子结构测定
6. Fundamental Studies of Carbon Oxygen Bond Activation in Nickel Diphosphine Ether Complexes. And, Metallomacrocycles as Ligands: Synthesis and Characterization of Aluminum-Bridged Bisglyoximato Complexes of Iron and Cobalt [O] . Kelley Paul 2014

机译：镍二膦醚配合物中碳氧键活化的基础研究。并且，金属大环化合物作为配体：铝桥联双乙氧基硅烷铁与钴配合物的合成与表征
7. Bis(Di-Isopropylamino) Phosphido and Di-Isopropylaminophosphinidene Metal Carbonyl Complexes from Reactions of Manganese and Cobalt Carbonyls with Bis(Di-Isopropylamino) Phosphine: X-Ray Crystal Structures of (Pr(i2)N)2PMn2 (CO)8H [R] . King, R. B., Fu, W. K., Holt, E. M. 1984

机译：双（二异丙基氨基）亚磷酰基和二异丙基氨基亚膦基金属羰基配合物来自锰和羰基钴与双（二异丙基氨基）膦的反应：（pr（i2）N）2pmn2（CO）8H的X射线晶体结构

Substitution chemistry of the cobalt complexes R carbon cobalt(3) nonacarbonyl (R = hydrogen, formyl radical) with the diphosphine ligand 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): Syntheses, x-ray structures, and reactivity.

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