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Chemistry of nanoscale carbon materials: Gas-phase purification of single-wall carbon nanotubes, synthesis of nanoscale carbon nitrides, and nanodiamonds in meteorite carbon with related diamond surface chemistry.

机译:纳米碳材料的化学:单壁碳纳米管的气相纯化,陨石碳中纳米碳氮化物和纳米金刚石的合成以及相关的金刚石表面化学。

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摘要

A unique feature of nanoscale carbon materials is the nature of their surfaces and how their surfaces interact with other species. The carbon materials specifically studied here include single-wall carbon nanotubes, nanoscale carbon nitrides, and a brief study of nanodiamonds from meteorite carbon, and related diamond surface chemistry. These nanometer sized carbon materials often possess curved surfaces. These curved surfaces can result in special structure-property relationships, such as a unique resistance to oxidation in the case of the nanotubes. Also the synthesis of nanoscale structures can be governed by surface interactions with the growth substrate, as shall be demonstrated with the carbon nitrides. The final materials obtained after such chemical treatments, should prove useful in applications such as catalysis, gas storage, chromatography, molecular electronics, high-strength composites, batteries and fuel cells, and abrasives.
机译:纳米碳材料的独特之处在于其表面的性质以及它们的表面如何与其他物种相互作用。这里专门研究的碳材料包括单壁碳纳米管,纳米级碳氮化物,以及对陨石碳纳米金刚石的简要研究,以及相关的金刚石表面化学。这些纳米级碳材料通常具有弯曲的表面。这些弯曲的表面可导致特殊的结构-特性关系,例如在纳米管的情况下具有独特的抗氧化性。纳米结构的合成也可以通过与生长基质的表面相互作用来控制,这将由碳氮化物证明。经过此类化学处理后获得的最终材料应证明可用于催化,气体存储,色谱,分子电子学,高强度复合材料,电池和燃料电池以及磨料等应用。

著录项

  • 作者

    Zimmerman, John Lynn.;

  • 作者单位

    Rice University.;

  • 授予单位 Rice University.;
  • 学科 Chemistry Inorganic.; Engineering Materials Science.
  • 学位 Ph.D.
  • 年度 2000
  • 页码 131 p.
  • 总页数 131
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 无机化学;工程材料学;
  • 关键词

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