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Design of advanced fibrous based material systems to meet the critical challenges in water quality and carbon dioxide mitigation.

机译:设计先进的纤维基材料系统,以应对水质和二氧化碳减排的严峻挑战。

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摘要

Water purification and global warming mitigation represent two of the major challenges in the 21st century. The research presented in this dissertation will describe the development of advanced fibrous systems that exhibit excellent performance in addressing the issues of water disinfection, carbon dioxide capture, and natural organic matter (NOM) removal from water.;Total eradication of E. coli was achieved with fiberglass impregnated with either silver (FG-Ag), iron oxide (Fe2O3 ) modified with Ag (FG-F2O3/Ag) or copper oxide (CuO) modified with Ag (FG-CuO/Ag). The Ag modified oligodynamic nanoparticle impregnated fiberglass displayed excellent kinetic inactivation performance with extended capacity at a much lower amount of nanoparticle loading. The results support their immediate applicability in the field from a utility and cost perspective.;The polyethyleneimine coated glass fibers (PEFA) for CO2 removal displayed high capacity for CO2 adsorption, up to 440 mg-CO 2/g while providing a mechanically durable and recyclable system for CO2 capture. The system offers the potential for CO2 utilization from the adsorbed CO2 from a power plant or closed environment (submarine, space shuttles or control rooms).;Aminated polyacrylonitrile activated carbon fibers (N-ACF) coated on a non-woven fiberglass mat, displayed the ability to remove NOM more efficiently than granulated activated carbon or ion exchange beads at concentrations below 50 mg/L. Electrostatic attraction was found to be the dominant mechanism of NOM adsorption for the N-ACF.
机译:水净化和缓解全球变暖是21世纪的两个主要挑战。本文介绍的研究将描述先进纤维系统的开发,这些系统在解决水消毒,二氧化碳捕集和从水中去除天然有机物(NOM)方面表现出卓越的性能。;实现了彻底根除大肠杆菌玻璃纤维浸有银(FG-Ag),经银改性的氧化铁(Fe2O3)(FG-F2O3 / Ag)或经银改性的氧化铜(CuO)(FG-CuO / Ag)。银改性的微动力学纳米粒子浸渍玻璃纤维表现出出色的动力学灭活性能,并且在低得多的纳米粒子负载量下具有扩展的容量。从实用性和成本的角度来看,这些结果支持了它们在该领域的即时适用性。聚乙烯亚胺涂层的玻璃纤维(PEFA)去除了CO2,显示出高的CO2吸附能力,高达440 mg-CO 2 / g,同时提供了机械耐久性和耐用性。可回收的二氧化碳捕集系统。该系统提供了发电厂或封闭环境(潜艇,航天飞机或控制室)中吸附的CO2的潜在利用CO2的功能;涂有无纺玻璃纤维毡的胺化聚丙烯腈活性碳纤维(N-ACF),展示与浓度低于50 mg / L的颗粒状活性炭或离子交换珠相比,去除NOM的效率更高。发现静电吸引是N-ACF吸附NOM的主要机理。

著录项

  • 作者

    Nangmenyi, Gordon.;

  • 作者单位

    University of Illinois at Urbana-Champaign.;

  • 授予单位 University of Illinois at Urbana-Champaign.;
  • 学科 Engineering Materials Science.
  • 学位 Ph.D.
  • 年度 2009
  • 页码 225 p.
  • 总页数 225
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 工程材料学;
  • 关键词

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