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Charge transfer complexations of buckminsterfullerene with substituted anilines and aromatics.

机译：buckminsterfullerene与取代的苯胺和芳烃的电荷转移络合物。

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The charge-transfer complexes of C60/substituted anilines and C60/condensed aromatic hydrocarbons were identified and analyzed using uv-vis electronic absorption spectroscopy. The aromatic amines used were aniline, 2,6-dimethylaniline, N,N-diethylaniline, N,N-dimethylaniline, and N-methylaniline. The charge transfer interactions of these compounds with C60 were studied in solvent solutions of dichloromethane and toluene at 25°C. The condensed aromatics used were naphthalene, phenanthrene, and pyrene. Their charge transfer interactions with C60 were studied in toluene solvent solutions at temperatures between 15 and 40°C.;Using the Benesi-Hildebrand analysis, the equilibrium constants (K) were determined for C60 charge-transfers interactions. For the C 60/aniline interaction, K = 0.28 +/- 0.04. For the interaction of C60/aromatic hydrocarbons, the K values are as follows: C 60/naphthalene K = 0.08 +/- 0.015, C60/phenanthrene K = 0.30 +/- 0.05, C60/pyrene K= 1.1 +/- 0.2.

机译：使用uv-vis电子吸收光谱法鉴定并分析了C60 /取代苯胺和C60 /稠合芳烃的电荷转移络合物。使用的芳族胺为苯胺，2，6-二甲基苯胺，N，N-二乙基苯胺，N，N-二甲基苯胺和N-甲基苯胺。在25℃的二氯甲烷和甲苯的溶剂溶液中研究了这些化合物与C60的电荷转移相互作用。所用的稠合芳族化合物是萘，菲和pyr。在15至40°C的温度下，研究了它们在甲苯溶剂溶液中与C60的电荷转移相互作用;使用Benesi-Hildebrand分析，确定了C60电荷转移相互作用的平衡常数（K）。对于C 60 /苯胺相互作用，K = 0.28 +/- 0.04。对于C60 /芳烃的相互作用，K值如下：C 60 /萘K = 0.08 +/- 0.015，C60 /菲K = 0.30 +/- 0.05，C60 / py K = 1.1 +/- 0.2。

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作者
Campbell, Robert Lee, Jr.;
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作者单位

San Jose State University.;

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授予单位 San Jose State University.;
学科 Engineering Materials Science.;Chemistry Organic.;Chemistry Physical.
学位 M.S.
年度 1999
页码 79 p.
总页数 79
原文格式 PDF
正文语种 eng
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专利

1. Spectroscopic and theoretical studies on the nucleophilic substitution of 2,3-dichloronaphthoquinone with para-substituted anilines in solid state via initial charge transfer complexation [J] . Satheshkumar A., Elango K.P. Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy . 2012,第Null期

机译：通过初始电荷转移络合以固态对位取代苯胺亲核取代2,3-二氯萘醌的光谱学和理论研究
2. Spectroscopic and Quantum Mechanical Studies of Substituted Anilines and their Charge-Transfer Complexes with Iodine in Different Solvents [J] . Tarek M.El-Gogary, Mostafa A.Diab, Shreen F.El-Tantawy Monatshefte fur Chemie . 2006,第8期

机译：不同溶剂中取代苯胺及其与碘的电荷转移配合物的光谱和量子力学研究
3. Studies on Charge-Transfer Complexes of 2,3-Dicyano-l,4-naphthoquinone with Some Ring and N-Substituted Anilines [J] . Gururaj M.Neelgund, M.L.Budni Monatshefte fur Chemie . 2004,第11期

机译：2,3-二氰基-1,4-萘醌与一些环和N-取代苯胺的电荷转移配合物的研究
4. Optical nonlinearity of buckminsterfullerene charge-transfer complex [C] . Yuxing Sun, Shao-chen Yang, Qihuang Gong, International conference on lasers and optoelectronics . 1993

机译：Caketminsterfullerene电荷转移复合物的光学非线性
5. I. Synthesis of substituted naphthalenes utilizing active nickel. II. Synthesis of substituted naphthoquinones and formation of a charge transfer complex. III. Synthesis of substituted 1,4-diphenyl-2-butenes from (eta(6):eta(6)-1,4-diphenyl-1,3-butadiene)-bis(tricarbonylchromium) [D] . Forkner, Matthew W. 1988

机译：I.利用活性镍合成取代的萘。二。取代萘醌的合成和电荷转移配合物的形成。三，由（eta（6）：eta（6）-1,4-二苯基-1,3-丁二烯）-双（三羰基铬）合成取代的1,4-二苯基-2-丁烯
6. Manipulating charge transfer excited state relaxation and spin crossover in iron coordination complexes with ligand substitution [O] . Wenkai Zhang, Kasper S. Kjær, Roberto Alonso-Mori, 2017

机译：在配体取代的铁配位配合物中操纵电荷转移激发态弛豫和自旋交叉
7. Comparing charge transfer tuning effects by chemical substitution and uniaxial pressure in the organic charge transfer complex tetramethoxypyrene-tetracyanoquinodimethane [O] . Rudloff, Milan, Ackermann, Kai, Huth, Michael, 2014

机译：通过化学替代和比较来比较电荷转移调谐效应有机电荷转移络合物中的单轴压力 tetramethoxypyrene，四氰基

Charge transfer complexations of buckminsterfullerene with substituted anilines and aromatics.

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