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A novel synthetic approach towards pentaprismane and isolation of the known cembranoid eunicin from the sea rod Pseudoplexaura sp.

机译：一种新的五戊烷合成方法，以及从海竿假单胞菌属种中分离出已知的类洋红素。

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art I. Varied successful applications, ranging from high-density explosives to medicinal compounds, clearly indicate that derivatives polycarbocyclic cage compounds possess a bright future. The wide application and promising future of (n) -prismane derivatives has helped to re-focus the attention of the synthetic chemist to devise a more concise, facile, and efficient synthetic route to this exciting, unique class of non-natural products. In particular to this class of compounds, pentaprismane has been recognized for its "synthetic inaccessibility." Thus, it is the goal of this project to develop an efficient synthesis that will not only yield pentaprismane, but that will also easily provide a pathway to the synthesis of pentaprismane's unexplored derivatives (DIAGRAM, TABLE OR GRAPHIC OMITTED...PLEASE SEE DAI).;This interest led us to investigate the tandem 1,3-dipolar cycloaddition reaction between munchnone 1 and 1,3,5,7-cyclooctatetraene (COT) as a novel facile route to the tetracyclo (6.3.0.0;Part II. Utilizing 2D NMR techniques we wish to report the total assignment of the

机译：从高密度炸药到药用化合物的各种成功应用清楚地表明，衍生物多碳环笼化合物具有光明的前景。（n）-ism烷衍生物的广泛应用和有希望的未来，有助于重新吸引合成化学家的注意力，从而为这种令人兴奋的独特的非天然产物设计一条更简洁，便捷和有效的合成路线。特别是对于这类化合物，五pen烷因其“合成不可及性”而得到公认。因此，本项目的目标是开发一种有效的合成方法，该方法不仅可以生成五pr烷，而且还可以轻松地为五pr烷未开发的衍生物（DIAGRAM，TABLE或GRAPHIC OGRATED ... PLEASE DAI）合成提供途径。。;这种兴趣使我们研究了蒙口酮1和1,3,5,7-环辛酸酯（COT）之间的串联1,3-偶极环加成反应，这是通向四环的一种新颖的简便途径（6.3.0.0;第二部分。我们希望报告2D NMR技术的总任务

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作者
Sponholtz, William Robert, III.;
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作者单位

Dartmouth College.;

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授予单位 Dartmouth College.;
学科 Organic chemistry.;Biochemistry.
学位 Ph.D.
年度 1998
页码 155 p.
总页数 155
原文格式 PDF
正文语种 eng
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1. Isolation and structure determination of the cembranoid eunicin from a new genus of octocoral, Pseudoplexaura. [J] . SponholtzW.R., BiancoM.A., GribbleG.W. Natural product research . 2008,第5期

机译：八叶类新植物伪丛中松柏中尤尼克霉素的分离和结构测定。
2. Isolation and structure determination of the cembranoid eunicin from a new genus of octocoral, Pseudoplexaura [J] . SponholtzW.R., BiancoM.A., GribbleG.W. Natural product research . 2008,第5期

机译：八叶新种Pseudoplexaura的本菌类洋红素的分离和结构测定
3. Synthetic studies toward tricyclic cembranoids:a modular approach for the construction of the tricyclic framework of eunicin [J] . Mukund K.Gurjar, Sabita Nayak, C.V.Ramana Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2005,第11期

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A novel synthetic approach towards pentaprismane and isolation of the known cembranoid eunicin from the sea rod Pseudoplexaura sp.

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