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Liquid phase synthesis of methanol/methyl formate under mild conditions.

机译：在温和条件下液相合成甲醇/甲酸甲酯。

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A slurry phase "concurrent" synthesis of MeOH/methyl formate (MeF) which operates under relatively mild conditions (100;Reaction studies indicated that the rate of MeOH formation is dependent on both the carbonylation and the hydrogenolysis reaction; the carbonylation reaction becomes more important at higher copper chromite loadings. The presence of small amounts of ;The effect of process parameters such as temperature, pressure, H;The equilibrium concentration of MeF in liquid decreases drastically with increasing temperature. Thermodynamic and reaction studies indicated that the synthesis is best carried out at a temperature in the range of 100-180

机译：在相对温和的条件下运行的甲醇/甲酸甲酯（MeF）的淤浆相“并发”合成（100；反应研究表明，MeOH的形成速率取决于羰基化和氢解反应；羰基化反应变得更加重要在亚铬酸铜较高的负载下；少量的存在；温度，压力，H等工艺参数的影响；液相中MeF的平衡浓度随温度的升高而急剧下降；热力学和反应研究表明，合成最佳进行在100-180的温度范围内

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作者
Palekar, Vishwesh Mahesh.;
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作者单位

University of Pittsburgh.;

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授予单位 University of Pittsburgh.;
学科 Chemical engineering.
学位 Ph.D.
年度 1993
页码 267 p.
总页数 267
原文格式 PDF
正文语种 eng
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1. METHANOL AND METHYL FORMATE SYNTHESIS FROM SYNTHESIS GAS OVER CUPROUS CHLORIDE CATALYST IN LIQUID PHASE [J] . Chen Wenkai Journal of Natural Gas Chemistry . 2000,第2期

机译：液相氯化铜催化剂上合成气合成甲醇和甲酸甲酯
2. Liquid-phase synthesis of methyl formate via heterogeneous carbonylation of methanol over a soluble copper nanocluster catalyst [J] . Ling He, Haichao Liu, Chao-xian Xiao Green chemistry . 2008,第6期

机译：在可溶性铜纳米簇催化剂上通过甲醇的非均相羰基化液相合成甲酸甲酯
3. Vapor-Liquid Equilibrium for Methoxymethane + Methyl Formate, Methoxymethane + Hexane, and Methyl Formate + Methanol [J] . Aarne T. Sundberg, Petri Uusi-Kyyny, Minna Pakkanen Journal of Chemical and Engineering Data: the ACS Journal for Data . 2011,第5期

机译：甲氧基甲烷+甲基甲酸酯，甲氧基甲烷+己烷和甲基甲酰胺+甲醇的汽液平衡
4. Kinetic Studies of the Vapour Phase Hydrogenolysis of Methyl Formate to Methanol on Copper-Based Catalysts [C] . X. Huang, J. W. Evans, M.S. Wainwright, Asia-Pacific Congress on Catalysis . 2003

机译：铜基催化剂对甲醇甲酯气相氢化的动力学研究
5. Methanol synthesis via methyl formate in the liquid phase. [D] . Liu, Zhenyu. 1988

机译：在液相中通过甲酸甲酯合成甲醇。
6. CuO Nanoparticle-Decorated TiO2-NanotubeHeterojunctions for Direct Synthesis of Methyl Formate via Photo-Oxidation of Methanol [O] . Shuwei Zhang, Xia Gong, Quanquan Shi, 2020

机译：CuO纳米颗粒修饰的TiO2-纳米管通过甲醇的光氧化直接合成甲基甲酸酯的异质结
7. Preparation of bifunctional Au-Pd/TiO2 catalysts and research on methanol liquid phase one-step oxidation to methyl formate [O] . Da Shi, Jianfang Liu, Rui Sun, 2018

机译：双官能AU-Pd / TiO2催化剂的制备及甲醇液相一步氧化对甲酸甲酯的研究
8. Liquid phase methanol LaPorte process development unit: Modification, operation, and support studies. Task 3.5: Development of fundamental rate models for methanol synthesis in a slurry reactor. [R] . 1991

机译：液相甲醇Laporte工艺开发单元：修改，操作和支持研究。任务3.5：开发浆料反应器中甲醇合成的基本速率模型。

Liquid phase synthesis of methanol/methyl formate under mild conditions.

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